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Mercury, diethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas90. ± 50.kJ/molAVGN/AAverage of 6 values; Individual data points

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid100.1 ± 4.2kJ/molReviewMartinho SimõesMS
Deltafliquid31.2 ± 5.2kJ/molReviewMartinho SimõesMS
Deltafliquid32.2 ± 5.3kJ/molReviewMartinho SimõesMS
Deltafliquid30.2 ± 1.5kJ/molReviewMartinho SimõesSelected data. Average of the values from Carson, Carson, et al., 1952 and Hartley, Pritchard, et al., 1951.; MS
Deltafliquid27.2 ± 0.8kJ/molCC-SBCarson, Carson, et al., 1952Value corrected based on a set of ancillary data by J.A. Martinho Simões; Please also see Cox and Pilcher, 1970. The enthalpy of combustion is not reported in Carson, Carson, et al., 1952.; MS
Quantity Value Units Method Reference Comment
Deltacliquid-3103.3 ± 4.2kJ/molCC-SBLautsch, Erzberger, et al., 1958Please also see Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
Deltafsolid72.0kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacsolid-3075.2kJ/molCC-SBBerthelot, 1899Please also see Berthelot, 1900.; MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
182.3298.15Burchalova, Kamelova, et al., 1978T = 5 to 300 K.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Carson, Carson, et al., 1952
Carson, A.S.; Carson, E.M.; Wilmshurst, B., Nature, 1952, 170, 320. [all data]

Hartley, Pritchard, et al., 1951
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. IV. Mercury diethyl and mercury diphenyl, Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Berthelot, 1899
Berthelot, M., Compt. Rend., 1899, 129, 918. [all data]

Berthelot, 1900
Berthelot, M., Ann. Chim. Phys., 1900, 20, 158. [all data]

Burchalova, Kamelova, et al., 1978
Burchalova, G.V.; Kamelova, G.P.; Nistratov, V.P.; Sheiman, M.S.; Rabinovich, I.B., Low-temperature heat capacity of diethylmercury, Termodin. Org. Soedin., 1978, (7), 21-22. [all data]


Notes

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