Camphor

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-319. ± 3.kJ/molCcbSteele, 1977ALS
Δfsolid-399. ± 66.kJ/molCcbDelafontaine, Sabbah, et al., 1973%hf298 calculated possible error by the authors; ALS
Quantity Value Units Method Reference Comment
Δcsolid-5902. ± 3.kJ/molCcbSteele, 1977Corresponding Δfsolid = -319. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5822. ± 66.kJ/molCcbDelafontaine, Sabbah, et al., 1973%hf298 calculated possible error by the authors; Corresponding Δfsolid = -400. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5891.2kJ/molCcbShchukarev and Shchukareva, 1932Corresponding Δfsolid = -330.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5898.6 ± 3.8kJ/molCcbSwietoslawski and Bobinska, 1929Corresponding Δfsolid = -323. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5910.7kJ/molCcbRoth and Ostling, 1913Corresponding Δfsolid = -311. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
271.2298.1Frandsen, 1931T = 307 to 483 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, 1977
Steele, W.V., The standard enthalpies of formation of bicyclic compounds. III. 1,7,7-trimethylbicyclo[2.2.1]heptan-2-one, J. Chem. Thermodyn., 1977, 9, 311-314. [all data]

Delafontaine, Sabbah, et al., 1973
Delafontaine, J.; Sabbah, R.; Laffitte, M., Mesures microcalorimetriques des enthalpies de reference de formation (a l'etat condense) de composes volatils - mise au point de la technique, Z. Phys. Chem. (Neue Folge), 1973, 84, 157-172. [all data]

Shchukarev and Shchukareva, 1932
Shchukarev, A.N.; Shchukareva, L.A., Heat standards, Russ. J. Phys. Chem. (Engl. Transl.), 1932, 3, 169-174. [all data]

Swietoslawski and Bobinska, 1929
Swietoslawski, M.W.; Bobinska, M.J., O cieple spalania kamfory, azobenzenu i hydrazobenzenu - Sur la chaleur de combustion du comphre, de l'hydrazobenzene, Rocz. Chem., 1929, 9, 723-730. [all data]

Roth and Ostling, 1913
Roth, W.A.; Ostling, G.J., Thermochemische Untersuchungen in der alicyclischen Reihe, Ber., 1913, 46, 309-327. [all data]

Frandsen, 1931
Frandsen, M., Cryoscopic constant, heat of fusion, and heat capacity of camphor, Bur. Stand. J. Res., 1931, 7, 477-483. [all data]


Notes

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