Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Chlorine difluoride-35cl


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 500 Ar Ra Prochaska and Andrews, 1977
1 Sym. stretch 536 w T N2 IR Mamantov, Vasini, et al., 1971
1 Sym. stretch 500 N2 Ra Prochaska and Andrews, 1977
2 Bend 242 w T N2 IR Mamantov, Vasini, et al., 1971
b2 3 Asym. stretch 574 s Ar IR Mamantov, Vasini, et al., 1971
Prochaska and Andrews, 1977
3 Asym. stretch 578 s N2 IR Mamantov, Vasini, et al., 1971
Prochaska and Andrews, 1977

Additional references: Jacox, 1994, page 116; Galbraith, Vacek, et al., 1993

Notes

wWeak
sStrong
TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prochaska and Andrews, 1977
Prochaska, E.S.; Andrews, L., Raman, infrared and ultraviolet spectra of the chlorine difluoride free radical in solid nitrogen, Inorg. Chem., 1977, 16, 2, 339, https://doi.org/10.1021/ic50168a023 . [all data]

Mamantov, Vasini, et al., 1971
Mamantov, G.; Vasini, E.J.; Moulton, M.C.; Vickroy, D.G.; Maekawa, T., Chlorine--Fluorine System at Low Temperatures: Characterization of the ClF2 Radical, J. Chem. Phys., 1971, 54, 8, 3419, https://doi.org/10.1063/1.1675359 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Galbraith, Vacek, et al., 1993
Galbraith, J.M.; Vacek, G.; Schaefer, H.F., III, ClF2: Structure and infrared spectra of a weakly bound triatomic molecule, J. Chem. Phys., 1993, 98, 10, 8051, https://doi.org/10.1063/1.464560 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References