Chlorine difluoride-35cl


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to ClF2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference
12.77 ± 0.05EIDudin, Gorokhov, et al., 1979

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 500 Ar Ra Prochaska and Andrews, 1977
1 Sym. stretch 536 w T N2 IR Mamantov, Vasini, et al., 1971
1 Sym. stretch 500 N2 Ra Prochaska and Andrews, 1977
2 Bend 242 w T N2 IR Mamantov, Vasini, et al., 1971
b2 3 Asym. stretch 574 s Ar IR Mamantov, Vasini, et al., 1971
Prochaska and Andrews, 1977
3 Asym. stretch 578 s N2 IR Mamantov, Vasini, et al., 1971
Prochaska and Andrews, 1977

Additional references: Jacox, 1994, page 116; Galbraith, Vacek, et al., 1993

Notes

wWeak
sStrong
TTentative assignment or approximate value

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dudin, Gorokhov, et al., 1979
Dudin, A.V.; Gorokhov, L.N.; Baluev, A.V., A study of the electron-impact ionization of chlorine trifluoride and its decomposition products by mass spectrometry, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1979, 11, 2408. [all data]

Prochaska and Andrews, 1977
Prochaska, E.S.; Andrews, L., Raman, infrared and ultraviolet spectra of the chlorine difluoride free radical in solid nitrogen, Inorg. Chem., 1977, 16, 2, 339, https://doi.org/10.1021/ic50168a023 . [all data]

Mamantov, Vasini, et al., 1971
Mamantov, G.; Vasini, E.J.; Moulton, M.C.; Vickroy, D.G.; Maekawa, T., Chlorine--Fluorine System at Low Temperatures: Characterization of the ClF2 Radical, J. Chem. Phys., 1971, 54, 8, 3419, https://doi.org/10.1063/1.1675359 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Galbraith, Vacek, et al., 1993
Galbraith, J.M.; Vacek, G.; Schaefer, H.F., III, ClF2: Structure and infrared spectra of a weakly bound triatomic molecule, J. Chem. Phys., 1993, 98, 10, 8051, https://doi.org/10.1063/1.464560 . [all data]


Notes

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