Benzene, 1,1'-methylenebis[4-isocyanato-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δcliquid-6912. ± 54.kJ/molCcbZalykin and Strepikheev, 1966ALS
Quantity Value Units Method Reference Comment
Δfsolid-53.0 ± 3.3kJ/molCcbLebedev, Evstropov, et al., 1977see Lebedev, Rabinovich, et al., 1977; ALS
Δfsolid-56. ± 13.kJ/molCcbZhuravlev, Selivanov, et al., 1975Heat of combustion by Selivanov and Konstantinov, 1970; ALS
Quantity Value Units Method Reference Comment
Δcsolid-7279. ± 3.3kJ/molCcbLebedev, Evstropov, et al., 1977see Lebedev, Rabinovich, et al., 1977; ALS
Δcsolid-7276. ± 13.kJ/molCcbSelivanov and Konstantinov, 1970ALS
Quantity Value Units Method Reference Comment
solid,1 bar332.5J/mol*KN/ALebedev, Evstropov, et al., 1977, 2DH
solid,1 bar332.5J/mol*KN/ALebedev, Rabinovich, et al., 1977, 2DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
307.0298.15Lebedev, Evstropov, et al., 1977, 2T = 12 to 355 K. Data deposited VINITI, No 4328-76, 14 December 1976.; DH
313.300.Lebedev, Rabinovich, et al., 1977, 2T = 13 to 400 K. Data given graphically. Value estimated from graph.; DH
244.8334.Zalikin and Strepikheev, 1966T = 46 to 78°C, mean value.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zalykin and Strepikheev, 1966
Zalykin, A.A.; Strepikheev, Yu.A., Certain physicochemical constants of 4,4'-diaminodiphenylmethane and diphenylmethane 4,4'diisocyanate, J. Appl. Chem. USSR (Engl. Transl.), 1966, 39, 2448, In original 2607. [all data]

Lebedev, Evstropov, et al., 1977
Lebedev, B.V.; Evstropov, A.A.; Sadikov, G.B.; Larina, L.F., Thermodynamics of di(4-isocyanatophenyl)methane, Russ. J. Phys. Chem. (Engl. Transl.), 1977, 51, 762-763. [all data]

Lebedev, Rabinovich, et al., 1977
Lebedev, B.V.; Rabinovich, I.B.; Kiparisova, E.G.; Evstropov, A.A.; Korshak, V.V.; Pankratov, V.A.; Larina, L.F., Thermodynamics of the polycyclotrimerization of aromatic dicyanates and diisocyanates, Dokl. Phys. Chem. (Engl. Transl.), 1977, 237, 1081-1084, In original 383. [all data]

Zhuravlev, Selivanov, et al., 1975
Zhuravlev, E.Z.; Selivanov, V.D.; Mulyanov, P.V.; Konstantinov, I.I., Physicochemical properties of 4,4'-dicyclohexylmethane diisocyanate, J. Appl. Chem. USSR, 1975, 1137-1139. [all data]

Selivanov and Konstantinov, 1970
Selivanov, V.D.; Konstantinov, I.I., Correction of the heat of combustion of diphenylmethane-4,4'-diisocyanate, J. Appl. Chem., 1970, 43, 2600-2601. [all data]

Lebedev, Evstropov, et al., 1977, 2
Lebedev, B.V.; Evstropov, A.A.; Sadikov, G.B.; Larina, L.F., Thermodynamics of di(4-isocyanatophenyl)methane, Zhur. Fiz. Khim., 1977, 51, 1285. [all data]

Lebedev, Rabinovich, et al., 1977, 2
Lebedev, B.V.; Rabinovich, I.B.; Kiparisova, Y.G.; Evstropov, A.A.; Korshak, V.V.; Pankratov, V.A.; Larina, L.F., Thermodynamics of the polycyclotrimerization of aromatic dicyanates and diisocyanates, Dokl. Akad. Nauk, 1977, SSSR 237, 383-386. [all data]

Zalikin and Strepikheev, 1966
Zalikin, A.A.; Strepikheev, Yu.A., Some physicochemical constants of 4,4'-diaminodiphenylmethane and 4,4'-diphenylmethanediisocyanate, Zhur. Priklad. Khim., 1966, 39, 2607. [all data]


Notes

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