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Tetracyano-p-quinodimethane

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.80 ± 0.30NBIECompton and Cooper, 1977The neutral HOF is not in 94PED, but this value agrees very well with G3B calculations.
2.80 ± 0.10NBIEKlots, Compton, et al., 1974Bound excited states: Brinkman, Gunther, et al., 1994.
2.80 ± 0.10SINazarenko and Pokhodenko, 1979The Magnetron method, lacking mass analysis, is not considered reliable.
2.88 ± 0.19SIFarragher and Page, 1967The Magnetron method, lacking mass analysis, is not considered reliable.

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Compton and Cooper, 1977
Compton, R.N.; Cooper, C.D., Negative ion properties of tetracyanoquinodimethane: Electron affinity and compound states, J. Chem. Phys., 1977, 66, 4325. [all data]

Klots, Compton, et al., 1974
Klots, C.E.; Compton, R.N.; Raaen, V.F., Electronic and ionic properties of of molecular TTF and TCMQ, J. Chem. Phys., 1974, 60, 1177. [all data]

Brinkman, Gunther, et al., 1994
Brinkman, E.A.; Gunther, E.; Schafer, O.; Brauman, J.I., Bound Excited Electronic States of Anions, J. Chem. Phys., 1994, 100, 3, 1840, https://doi.org/10.1063/1.466535 . [all data]

Nazarenko and Pokhodenko, 1979
Nazarenko, V.A.; Pokhodenko, V.D., The formation of negative ions in high electric fields, Int. J. Mass Spectrom. Ion Phys., 1979, 31, 381. [all data]

Farragher and Page, 1967
Farragher, A.L.; Page, F.M., Experimental Determination of Electron Affinities. Part 11. - Electron Capture by Some Cyanocarbons and Related Compounds, Trans. Farad. Soc., 1967, 63, 2369, https://doi.org/10.1039/tf9676302369 . [all data]


Notes

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