silver

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 12595-35-6 • 4294967295silver) + silver = CAS Reg. No. 12595-35-6

By formula: (CAS Reg. No. 12595-35-6 • 4294967295Ag) + Ag = CAS Reg. No. 12595-35-6

Quantity Value Units Method Reference Comment
Δr219. ± 7.5kJ/molLPDShi, Spasov, et al., 1999gas phase
Δr230. ± 9.6kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag7- loss; Ag8- loss ca. 0.07 eV higher.

(CAS Reg. No. 12595-37-8 • 4294967295silver) + silver = CAS Reg. No. 12595-37-8

By formula: (CAS Reg. No. 12595-37-8 • 4294967295Ag) + Ag = CAS Reg. No. 12595-37-8

Quantity Value Units Method Reference Comment
Δr230. ± 7.5kJ/molLPDShi, Spasov, et al., 1999gas phase
Δr238. ± 9.6kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag10- loss; Ag9- loss comparable.

(CAS Reg. No. 12595-33-4 • 4294967295silver) + silver = CAS Reg. No. 12595-33-4

By formula: (CAS Reg. No. 12595-33-4 • 4294967295Ag) + Ag = CAS Reg. No. 12595-33-4

Quantity Value Units Method Reference Comment
Δr239. ± 7.5kJ/molLPDShi, Spasov, et al., 1999gas phase
Δr264. ± 9.6kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag6- loss; Ag5- loss comparable.

(CAS Reg. No. 12595-34-5 • 4294967295silver) + silver = CAS Reg. No. 12595-34-5

By formula: (CAS Reg. No. 12595-34-5 • 4294967295Ag) + Ag = CAS Reg. No. 12595-34-5

Quantity Value Units Method Reference Comment
Δr159.2 ± 3.8kJ/molLPDShi, Spasov, et al., 1999gas phase
Δr174. ± 13.kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag7- loss as sole channel.

(CAS Reg. No. 12595-36-7 • 4294967295silver) + silver = CAS Reg. No. 12595-36-7

By formula: (CAS Reg. No. 12595-36-7 • 4294967295Ag) + Ag = CAS Reg. No. 12595-36-7

Quantity Value Units Method Reference Comment
Δr175.6 ± 3.8kJ/molLPDShi, Spasov, et al., 1999gas phase
Δr187. ± 15.kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag9- loss as sole channel.

(CAS Reg. No. 12595-31-2 • 4294967295silver) + silver = CAS Reg. No. 12595-31-2

By formula: (CAS Reg. No. 12595-31-2 • 4294967295Ag) + Ag = CAS Reg. No. 12595-31-2

Quantity Value Units Method Reference Comment
Δr177. ± 19.kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag3- loss; Ag4- loss ca. 0.29 eV higher.

(CAS Reg. No. 66525-32-4 • 4294967295silver) + silver = CAS Reg. No. 66525-32-4

By formula: (CAS Reg. No. 66525-32-4 • 4294967295Ag) + Ag = CAS Reg. No. 66525-32-4

Quantity Value Units Method Reference Comment
Δr223. ± 9.6kJ/molCIDTSpasov, Lee, et al., 1999gas phase; for loss of Ag-; Ag2- loss is 0.30 eV higher

(CAS Reg. No. 12595-28-7 • 4294967295silver) + silver = CAS Reg. No. 12595-28-7

By formula: (CAS Reg. No. 12595-28-7 • 4294967295Ag) + Ag = CAS Reg. No. 12595-28-7

Quantity Value Units Method Reference Comment
Δr131. ± 23.kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag3- loss; Ag2- loss ca. 0.3 eV higher.

(CAS Reg. No. 12595-32-3 • 4294967295silver) + silver = CAS Reg. No. 12595-32-3

By formula: (CAS Reg. No. 12595-32-3 • 4294967295Ag) + Ag = CAS Reg. No. 12595-32-3

Quantity Value Units Method Reference Comment
Δr170. ± 59.kJ/molCIDTSpasov, Lee, et al., 1999gas phase; For Ag4- loss; Ag5- loss ca. 0.05 eV higher.

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shi, Spasov, et al., 1999
Shi, Y.; Spasov, V.A.; Ervin, K.M., Competitive fragmentation and electron loss kinetics of photoactivated silver cluster anions: Dissociation energies of Ag-n(-) (n=7-11), J. Chem. Phys., 1999, 111, 3, 938-949, https://doi.org/10.1063/1.479186 . [all data]

Spasov, Lee, et al., 1999
Spasov, V.A.; Lee, T.H.; Maberry, J.P.; Ervin, K.M., Measurement of the dissociation energies of anionic silver clusters (Ag-n(-), n = 2-11) by collision-induced dissociation, J. Chem. Phys., 1999, 110, 11, 5208-5217, https://doi.org/10.1063/1.478416 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References