Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Sulfur fluoride anion


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SF stretch 795.8 Ne IR Lugez, Jacox, et al., 1998
1 SF a-stretch 795.5 m Ar IR Smardzewski and Fox, 1977
Hassanzadeh and Andrews, 1992
e 7 SF stretch 602.9 Ne IR Lugez, Jacox, et al., 1998
7 SF stretch 596 s Ar IR Barefield and Guillory, 1977
Smardzewski and Fox, 1977
8 Deformation 470.5 Ne IR Lugez, Jacox, et al., 1998
8 470 w Ar IR Smardzewski and Fox, 1977

Additional references: Jacox, 1994, page 359; Jacox, 2003, page 333

Notes

wWeak
mMedium
sStrong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; King, R.A.; Schaefer, H.F., III, Experimental and ab initio study of the infrared spectra of ionic species derived from SF[sub 6] and SF[sub 4] and trapped in solid neon, J. Chem. Phys., 1998, 108, 23, 9639, https://doi.org/10.1063/1.476440 . [all data]

Smardzewski and Fox, 1977
Smardzewski, R.R.; Fox, W.B., Vacuum ultraviolet photolysis of sulfur hexafluoride and its derivatives in argon matrices. The infrared spectrum of the SF5 radical, J. Chem. Phys., 1977, 67, 5, 2309, https://doi.org/10.1063/1.435066 . [all data]

Hassanzadeh and Andrews, 1992
Hassanzadeh, P.; Andrews, L., Matrix reactions of sulfur atoms and fluorine. Infrared spectra of sulfur monofluoride, sulfur difluoride and sulfur trifluoride in solid argon, J. Phys. Chem., 1992, 96, 1, 79, https://doi.org/10.1021/j100180a018 . [all data]

Barefield and Guillory, 1977
Barefield, J.E., II; Guillory, W.A., Infrared spectroscopic evidence for matrix-isolated sulfur hexafluoride(1-) ion, J. Phys. Chem., 1977, 81, 7, 634, https://doi.org/10.1021/j100522a009 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References