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Sulfur fluoride anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar315.42J/mol*KReviewChase, 1998Data last reviewed in December, 1977

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

By formula: (F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar15.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

F5S- + Hydrogen sulfide = (F5S- bullet Hydrogen sulfide)

By formula: F5S- + H2S = (F5S- bullet H2S)

Quantity Value Units Method Reference Comment
Deltar212. ± 48.kJ/molSIFTZangerle, Hansel, et al., 1993gas phase; CID with Ar

F5S- + F6S- = (F5S- bullet F6S-)

By formula: F5S- + F6S- = (F5S- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

F5S- + F6S- = (F5S- bullet F6S-)

By formula: F5S- + F6S- = (F5S- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

(F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

By formula: (F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar15.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase

F5S- + Hydrogen sulfide = (F5S- bullet Hydrogen sulfide)

By formula: F5S- + H2S = (F5S- bullet H2S)

Quantity Value Units Method Reference Comment
Deltar212. ± 48.kJ/molSIFTZangerle, Hansel, et al., 1993gas phase; CID with Ar

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SF stretch 795.8 Ne IR Lugez, Jacox, et al., 1998
1 SF a-stretch 795.5 m Ar IR Smardzewski and Fox, 1977
Hassanzadeh and Andrews, 1992
e 7 SF stretch 602.9 Ne IR Lugez, Jacox, et al., 1998
7 SF stretch 596 s Ar IR Barefield and Guillory, 1977
Smardzewski and Fox, 1977
8 Deformation 470.5 Ne IR Lugez, Jacox, et al., 1998
8 470 w Ar IR Smardzewski and Fox, 1977

Additional references: Jacox, 1994, page 359; Jacox, 2003, page 333

Notes

wWeak
mMedium
sStrong

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M. Fujimaki, Gas-Phase Stability of Cluster Ions SFm+(SF6)n with m = 0-5 and n = 1-3, J. Am. Soc. Mass Spectrom., 1995, 6, 12, 1137, https://doi.org/10.1016/1044-0305(95)00583-8 . [all data]

Zangerle, Hansel, et al., 1993
Zangerle, R.; Hansel, A.; Richter, R.; Lindinger, W., The Reaction of SF5+ + H2S at Near Thermal Energies: Competition between Association and Binary Reactions, Int. J. Mass Spectrom. Ion Proc., 1993, 129, 117, https://doi.org/10.1016/0168-1176(93)87035-Q . [all data]

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; King, R.A.; Schaefer, H.F., III, Experimental and ab initio study of the infrared spectra of ionic species derived from SF[sub 6] and SF[sub 4] and trapped in solid neon, J. Chem. Phys., 1998, 108, 23, 9639, https://doi.org/10.1063/1.476440 . [all data]

Smardzewski and Fox, 1977
Smardzewski, R.R.; Fox, W.B., Vacuum ultraviolet photolysis of sulfur hexafluoride and its derivatives in argon matrices. The infrared spectrum of the SF5 radical, J. Chem. Phys., 1977, 67, 5, 2309, https://doi.org/10.1063/1.435066 . [all data]

Hassanzadeh and Andrews, 1992
Hassanzadeh, P.; Andrews, L., Matrix reactions of sulfur atoms and fluorine. Infrared spectra of sulfur monofluoride, sulfur difluoride and sulfur trifluoride in solid argon, J. Phys. Chem., 1992, 96, 1, 79, https://doi.org/10.1021/j100180a018 . [all data]

Barefield and Guillory, 1977
Barefield, J.E., II; Guillory, W.A., Infrared spectroscopic evidence for matrix-isolated sulfur hexafluoride(1-) ion, J. Phys. Chem., 1977, 81, 7, 634, https://doi.org/10.1021/j100522a009 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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