Methylene

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 60291-30-7 • 4294967295Methylene) + Methylene = CAS Reg. No. 60291-30-7

By formula: (CAS Reg. No. 60291-30-7 • 4294967295CH2) + CH2 = CAS Reg. No. 60291-30-7

Quantity Value Units Method Reference Comment
Δr21.1 ± 1.6kcal/molCIDTPoutsma, Nash, et al., 1997gas phase; B
Δr21.8 ± 3.0kcal/molTherHierl, Henchman, et al., 1992gas phase; HO- + MeBr:6.0±2.3 kcal/mol endo. "Better than Ingemann and Nibbering, 19852" 2.0 kcal would not show barrier; B
Δr24.4 ± 6.4kcal/molTherIngemann and Nibbering, 1985, 2gas phase; B

(CAS Reg. No. 60291-29-4 • 4294967295Methylene) + Methylene = CAS Reg. No. 60291-29-4

By formula: (CAS Reg. No. 60291-29-4 • 4294967295CH2) + CH2 = CAS Reg. No. 60291-29-4

Quantity Value Units Method Reference Comment
Δr28.4 ± 3.2kcal/molN/AIngemann and Nibbering, 1985, 2gas phase; B
Δr23.1 ± 2.9kcal/molCIDTPoutsma, Nash, et al., 1997gas phase; B

CH- + Hydrogen cation = Methylene

By formula: CH- + H+ = CH2

Quantity Value Units Method Reference Comment
Δr386.05 ± 0.44kcal/molD-EAKasdan, Herbst, et al., 1975gas phase; B
Quantity Value Units Method Reference Comment
Δr379.29 ± 0.53kcal/molH-TSKasdan, Herbst, et al., 1975gas phase; B

(CH3- • 4294967295Methylene) + Methylene = CH3-

By formula: (CH3- • 4294967295CH2) + CH2 = CH3-

Quantity Value Units Method Reference Comment
Δr94.98 ± 0.80kcal/molN/AEllison, Engelking, et al., 1978gas phase; B

Lanthanum ion (1+) + Methylene = (Lanthanum ion (1+) • Methylene)

By formula: La+ + CH2 = (La+ • CH2)

Quantity Value Units Method Reference Comment
Δr98.2 ± 1.4kcal/molCIDTSunderlin and Armentrout, 1989RCD

Scandium ion (1+) + Methylene = (Scandium ion (1+) • Methylene)

By formula: Sc+ + CH2 = (Sc+ • CH2)

Quantity Value Units Method Reference Comment
Δr98.3 ± 5.3kcal/molCIDTSunderlin and Armentrout, 1989RCD

Yttrium ion (1+) + Methylene = (Yttrium ion (1+) • Methylene)

By formula: Y+ + CH2 = (Y+ • CH2)

Quantity Value Units Method Reference Comment
Δr95.2 ± 3.0kcal/molCIDTSunderlin and Armentrout, 1989RCD

Cobalt ion (1+) + Methylene = (Cobalt ion (1+) • Methylene)

By formula: Co+ + CH2 = (Co+ • CH2)

Quantity Value Units Method Reference Comment
Δr75.9 ± 1.2kcal/molCIDTHaynes and Armentrout, 1994RCD

Chromium ion (1+) + Methylene = (Chromium ion (1+) • Methylene)

By formula: Cr+ + CH2 = (Cr+ • CH2)

Quantity Value Units Method Reference Comment
Δr53.8 ± 1.9kcal/molCIDTGeorgiadis and Armentrout, 1989RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Poutsma, Nash, et al., 1997
Poutsma, J.C.; Nash, J.J.; Paulino, J.A.; Squires, R.R., Absolute Heats of Formation of Phenylcarbene and Vinylcarbene, J. Am. Chem. Soc., 1997, 119, 20, 4686, https://doi.org/10.1021/ja963918s . [all data]

Hierl, Henchman, et al., 1992
Hierl, P.M.; Henchman, M.J.; Paulson, J.F., Threshold Energies for the Reactions HO- + MeX - MeOH + X- measured by Tandem Mass Spectrometry: Acidities of MeCl and MeBr, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 475, https://doi.org/10.1016/0168-1176(92)80109-E . [all data]

Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M., Gas phase chemistry of alpha-thio carbanions, Can. J. Chem., 1985, 62, 2273. [all data]

Ingemann and Nibbering, 1985, 2
Ingemann, S.; Nibbering, N.M.M., Gas-phase acidity of CH3X [X = P(CH3)2, SCH3, F, Cl, Br, I] compounds, J. Chem. Soc. Perkin Trans. 2, 1985, 837. [all data]

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of CH2-, Chem. Phys. Lett., 1975, 31, 78. [all data]

Ellison, Engelking, et al., 1978
Ellison, G.B.; Engelking, P.C.; Lineberger, W.C., An experimental determination of the geometry and electron affinity of CH3, J. Am. Chem. Soc., 1978, 100, 2556. [all data]

Sunderlin and Armentrout, 1989
Sunderlin, L.S.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with Methane and Ethane, J. Am. Chem. Soc., 1989, 111, 11, 3845, https://doi.org/10.1021/ja00193a015 . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Georgiadis and Armentrout, 1989
Georgiadis, R.; Armentrout, P.B., Reactions of Ground State Cr+ with C2H6, C2H4, cyclo-C3H6, and cyclo-C2H4O: Bond Energies for CrCHn+ (n= 1-3), Int. J. Mass Spectrom. Ion Proc., 1989, 89, 2-3, 227, https://doi.org/10.1016/0168-1176(89)83062-9 . [all data]


Notes

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