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Ethene, fluoro-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-136.kJ/molCcrKolesov and Papina, 1970 
Quantity Value Units Method Reference Comment
Deltacgas-1256. ± 2.kJ/molCcrKolesov and Papina, 1970 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H2F- + Hydrogen cation = Ethene, fluoro-

By formula: C2H2F- + H+ = C2H3F

Quantity Value Units Method Reference Comment
Deltar1618. ± 17.kJ/molG+TSRabasco and Kass, 1992gas phase; Comparable to PhF. Vinyl anion structure proved, rxn with D2O -> more stable HC«equiv»CH..F-; B
Quantity Value Units Method Reference Comment
Deltar1586. ± 17.kJ/molIMRBRabasco and Kass, 1992gas phase; Comparable to PhF. Vinyl anion structure proved, rxn with D2O -> more stable HC«equiv»CH..F-; B

Fluorine anion + Ethene, fluoro- = (Fluorine anion bullet Ethene, fluoro-)

By formula: F- + C2H3F = (F- bullet C2H3F)

Quantity Value Units Method Reference Comment
Deltar65. ± 17.kJ/molIMRBSullivan and Beauchamp, 1976gas phase; B

Ethene, fluoro- + hydrogen fluoride = Ethane, 1,1-difluoro-

By formula: C2H3F + HF = C2H4F2

Quantity Value Units Method Reference Comment
Deltar-50.kJ/molEqkMoore, 1971gas phase; ALS

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kolesov and Papina, 1970
Kolesov, V.P.; Papina, T.S., Standard enthalpy of formation of vinyl fluoride, Russ. J. Phys. Chem. (Engl. Transl.), 1970, 44, 611-613. [all data]

Rabasco and Kass, 1992
Rabasco, J.J.; Kass, S.R., Reactions of Strong Bases with Vinyl Fluoride Formation and Characterization of 1-Fluorovinyl Anion and the Fluoride-Acetylene Hydrogen-Bond, J. Am. Soc. Mass Spectrom., 1992, 3, 2, 91, https://doi.org/10.1016/1044-0305(92)87041-V . [all data]

Sullivan and Beauchamp, 1976
Sullivan, S.A.; Beauchamp, J.L., Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity, J. Am. Chem. Soc., 1976, 98, 1160. [all data]

Moore, 1971
Moore, L.O., Kinetics and thermodynamic data for the hydrogen fluoride addition to vinyl fluoride, Can. J. Chem., 1971, 49, 2471-2475. [all data]


Notes

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