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Propylene Carbonate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil513.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil515.05KN/ARajapakse, Finston, et al., 1986Uncertainty assigned by TRC = 0.7 K; TRC
Quantity Value Units Method Reference Comment
Tfus222.95KN/ARajapakse, Finston, et al., 1986Uncertainty assigned by TRC = 1. K; TRC
Tfus222.95KN/AHong, Waksiak, et al., 1982Uncertainty assigned by TRC = 0.3 K; TRC
Tfus218.62KN/AJones and Aikens, 1982Uncertainty assigned by TRC = 0.06 K; TRC
Quantity Value Units Method Reference Comment
Ttriple218.66KN/AFujimori and Oguni, 1994Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple224.85KN/AVasil'ev and Petrov, 1984Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple224.85KN/AVasil'ev, Korkhov, et al., 1976Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltavap60. ± 30.kJ/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
54.4427.AStephenson and Malanowski, 1987Based on data from 412. - 466. K.; AC
33.8338.A,MMStephenson and Malanowski, 1987Based on data from 323. - 370. K. See also Choi and Joncich, 1971.; AC
57.8383.EBHong, Wakslak, et al., 1982Based on data from 368. - 462. K.; AC
55.2423.EBHong, Wakslak, et al., 1982Based on data from 368. - 462. K.; AC
53.0443.EBHong, Wakslak, et al., 1982Based on data from 368. - 462. K.; AC
55.2323.N/AGranzhan and Salganikova, 1972Based on data from 293. - 353. K.; AC
55.229423.VPeppel, 1958ALS

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
9.617224.85N/AVasil'ev, Korkhov, et al., 1976, 2DH
9.617224.85N/AVasil'ev and Korkhov, 1974DH
8.96220.3DSCDing, 2004AC
8.01218.7ACFujimori and Oguni, 1994, 2Based on data from 13. - 300. K.; AC
9.62218.2N/AVasil'ev and Korkhov, 1974, 2AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
42.8224.85Vasil'ev, Korkhov, et al., 1976, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Rajapakse, Finston, et al., 1986
Rajapakse, N.; Finston, H.L.; Fried, V., J. Chem. Eng. Data, 1986, 31, 408. [all data]

Hong, Waksiak, et al., 1982
Hong, C.S.; Waksiak, R.; Finston, H.; Fried, V., Some Thermodynamic Properties of Systems Containing Propylene Carbonate and Ethylene Carbonate, J. Chem. Eng. Data, 1982, 27, 146. [all data]

Jones and Aikens, 1982
Jones, A.R.; Aikens, D.A., Propylene carbonate cryoscopy., J. Chem. Eng. Data, 1982, 27, 24-5. [all data]

Fujimori and Oguni, 1994
Fujimori, H.; Oguni, M., Calorimetric study of D,L-propene carbonate: observation of the «beta»- as well as «alpha»-glass transition in the supercooled liquid, J. Chem. Thermodyn., 1994, 26, 367. [all data]

Vasil'ev and Petrov, 1984
Vasil'ev, I.A.; Petrov, V.M., Thermodynamic Properties of Oxygen-containing Organic Compounds, Handbook, Soedinenii: Khimya, Leningrad, p 240, 1984. [all data]

Vasil'ev, Korkhov, et al., 1976
Vasil'ev, I.A.; Korkhov, A.D.; Minkin, D.M.; Rabinovich, I.B.; Sheiman, M.S.; Nistratov, V.P., Heat capacity and thermodynamic functions of propylene carbonate., Termodin. Org. Soedin., 1976, No. 5, 21. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J., Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation, J. Chem. Eng. Data, 1971, 16, 87-90. [all data]

Hong, Wakslak, et al., 1982
Hong, C.S.; Wakslak, R.; Finston, H.; Fried, V., Some thermodynamic properties of systems containing propylene carbonate and ethylene carbonate, J. Chem. Eng. Data, 1982, 27, 2, 146-148, https://doi.org/10.1021/je00028a012 . [all data]

Granzhan and Salganikova, 1972
Granzhan, V.A.; Salganikova, E.A., Tr. Nauch. Issled. Proekt. Inst. Azotn. Prom. Prod. Org. Sin., 1972, 16, 85. [all data]

Peppel, 1958
Peppel, W.J., Preparation and properties of the alkylene carbonates, Ind. Eng. Chem., 1958, 50, 767-770. [all data]

Vasil'ev, Korkhov, et al., 1976, 2
Vasil'ev, I.A.; Korkhov, A.D.; Minkin, D.M.; Rabinovich, I.B.; Sheiman, M.S.; Nistratov, V.P., Heat capacity and thermodynamic functions for propylene carbonate. Termodin. Org. Soedin., 1976, 21-26. [all data]

Vasil'ev and Korkhov, 1974
Vasil'ev, I.A.; Korkhov, A.D., Thermodynamic properties of alkylene carbonates at low temperatures, Tr. Khim. Khim. Tekhnol., Gor'kii, 1974, 36, 103-105. [all data]

Ding, 2004
Ding, Michael S., Liquid-Solid Phase Equilibria and Thermodynamic Modeling for Binary Organic Carbonates, J. Chem. Eng. Data, 2004, 49, 2, 276-282, https://doi.org/10.1021/je034134e . [all data]

Fujimori and Oguni, 1994, 2
Fujimori, Hiroki; Oguni, Masaharu, Calorimetric study of l,d-propene carbonate: observation of the «beta»- as well as «alpha»-glass transition in the supercooled liquid, The Journal of Chemical Thermodynamics, 1994, 26, 4, 367-378, https://doi.org/10.1006/jcht.1994.1046 . [all data]

Vasil'ev and Korkhov, 1974, 2
Vasil'ev, I.A.; Korkhov, A.D., Tr. Khim. Khim. Tekhnol., 1974, 103. [all data]


Notes

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