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Methyl vinyl sulfide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C3H6S+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)858.2kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity829.3kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.45PEMuller, Schafer, et al., 1976Vertical value; LLK
8.44PEPlanckaert, Doucet, et al., 1974Vertical value; LLK
8.45PEBock, Wagner, et al., 1974Vertical value; LLK
8.45PEBock, Wagner, et al., 1972Vertical value; LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Muller, Schafer, et al., 1976
Muller, C.; Schafer, W.; Schweig, A.; Thon, N.; Vermeer, H., Detection of rotational isomers by variable temperature photoelectron spectroscopy. A new technique in the realm of molecular conformational analysis, J. Am. Chem. Soc., 1976, 98, 5440. [all data]

Planckaert, Doucet, et al., 1974
Planckaert, A.A.; Doucet, J.; Sandorfy, C., Comparative study of the vacuum ultraviolet absorption and photoelectron spectra of some simple ethers and thioethers, J. Chem. Phys., 1974, 60, 4846. [all data]

Bock, Wagner, et al., 1974
Bock, H.; Wagner, G.; Wittel, K.; Sauer, J.; Seebach, D., Photoelektronenspektren und molekuleigenschaften. XXXII. n/«pi»-konjugation in heterosubstituierten athylenen, Chem. Ber., 1974, 107, 1869. [all data]

Bock, Wagner, et al., 1972
Bock, H.; Wagner, G.; Kroner, J., Photoelektronenspektren und molekuleigenschaften, XIV. Die delokalisation des schwefel-elektronenpaar in CH3S-substituierten aromaten, Chem. Ber., 1972, 105, 3850. [all data]


Notes

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