1,5-Cyclooctadiene, (Z,Z)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas101.0 ± 1.4kJ/molCcbKozina, Timofeeva, et al., 1976 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid57.7 ± 1.4kJ/molCcbKozina, Timofeeva, et al., 1976 
Quantity Value Units Method Reference Comment
Δcliquid-4920.8 ± 1.3kJ/molCcbKozina, Timofeeva, et al., 1976Corresponding Δfliquid = 57.70 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-4880.6kJ/molCcrRauh, Geyer, et al., 1973Corresponding Δfliquid = 18. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil420.KN/ATreboganov, Mitsner, et al., 1965Uncertainty assigned by TRC = 2. K; TRC
Tboil421.KN/AZakharkin and Zhigareva, 1963Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tfus203.KN/AZiegler and Wilms, 1948Uncertainty assigned by TRC = 5. K; stereochemistry not certain; TRC
Quantity Value Units Method Reference Comment
Δvap43.39kJ/molN/AMajer and Svoboda, 1985 
Δvap43.4 ± 0.1kJ/molCVarushchenko, Pashchenko, et al., 1996AC
Δvap43.3kJ/molN/AKozina, Timofeeva, et al., 1976DRB
Δvap41.0kJ/molVRauh, Geyer, et al., 1973ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C18H27ClRu (solution) + Benzeneethanamine, 3,4-dimethoxy- (solution) = C16H31ClP2Ru (solution) + 1,5-Cyclooctadiene, (Z,Z)- (solution)

By formula: C18H27ClRu (solution) + C10H15NO2 (solution) = C16H31ClP2Ru (solution) + C8H12 (solution)

Quantity Value Units Method Reference Comment
Δr-145.6 ± 0.8kJ/molRSCLuo, Zhu, et al., 1994solvent: Tetrahydrofuran; The enthalpy of solution of Ru(Cp*)(cod)(Cl)(cr) was measured as 20.5 ± 0.8 kJ/mol Luo, Nolan, et al., 1993.

Nickel, bis[(1,2,5,6-η)-1,5-cyclooctadiene]- (solution) = 21,5-Cyclooctadiene, (Z,Z)- (solution) + nickel (cr)

By formula: (Ni(C8H12)2) (solution) = 2C8H12 (solution) + Ni (cr)

Quantity Value Units Method Reference Comment
Δr-12.6 ± 4.2kJ/molRSCTolman, Reutter D.W., et al., 1976solvent: Toluene; The toluene solution contained catalytic amounts of carbon tetrachloride.

Rhodium, bis(η2-ethene)(2,4-pentanedionato-O,O')- (solution) + 1,5-Cyclooctadiene, (Z,Z)- (solution) = C13H19O2Rh (solution) + 2Ethylene (solution)

By formula: C9H15O2Rh (solution) + C8H12 (solution) = C13H19O2Rh (solution) + 2C2H4 (solution)

Quantity Value Units Method Reference Comment
Δr-9.0 ± 0.4kJ/molRSCJesse, Cordfunke, et al., 1979solvent: n-Heptane

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 1406

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Timofeeva, et al., 1976
Kozina, M.P.; Timofeeva, L.P.; Gal'chenko, G.L.; Gvozdeva, E.A.; Cherednichenko, V.M., The determination of the enthalphy of combustion of cis, cis-cyclooctadiene-1,5, Termodin. Org. Soedin., 1976, 9-11. [all data]

Rauh, Geyer, et al., 1973
Rauh, H.J.; Geyer, W.; Schmidt, H.; Geiseler, G., Bildungsenthalpien und mesomerieenergien von π-bindungssystemen, Z. Phys. Chem. (Leipzig), 1973, 253, 43-48. [all data]

Treboganov, Mitsner, et al., 1965
Treboganov, A.D.; Mitsner, B.I.; Zinkevich, E.P.; Kraevskii, A.A.; Preobrazhenskii, N.A., Macrocyclic compounds. I. Synthesis of cyclooctane and cyclododecane, Zh. Organ. Khim., 1965, 1, 1583-6. [all data]

Zakharkin and Zhigareva, 1963
Zakharkin, L.I.; Zhigareva, G.G., Dimerization of butadiene to cis-cis-1,5-cyclooctadiene catalyzed by pi-complex compounds of nickel, Izv. Akad. Nauk SSSR, 1963, Otd. Khim. Nauk 386 1963 1963. [all data]

Ziegler and Wilms, 1948
Ziegler, K.; Wilms, H., Stereoisomerism of Eight-membered Cycloolefin Rings, Naturwissenschaften, 1948, 35, 157-8. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Varushchenko, Pashchenko, et al., 1996
Varushchenko, R.M.; Pashchenko, L.L.; Druzhinina, A.I., Enthalpies of vaporization of some mono- and polycyclic hydrocarbons, Zh. Fiz. Khim., 1996, 70, 2, 228. [all data]

Luo, Zhu, et al., 1994
Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E.D.; Nolan, S.P.; Fagan, P.J., Organometallics, 1994, 13, 669. [all data]

Luo, Nolan, et al., 1993
Luo, L.; Nolan, S.P.; Fagan, P.J., Organometallics, 1993, 12, 4305. [all data]

Tolman, Reutter D.W., et al., 1976
Tolman, C.A.; Reutter D.W.; Seidel, W.C., J. Organometal. Chem., 1976, 117, C30. [all data]

Jesse, Cordfunke, et al., 1979
Jesse, A.C.; Cordfunke, E.H.P.; Ouweltjes, W., Thermochim. Acta, 1979, 30, 293. [all data]


Notes

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