HCSNH2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 82400 ± 1000 gas Kimura, Katsumata, et al., 1976

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 72700 ± 1000 gas Kimura, Katsumata, et al., 1976

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 55110 ± 320 gas Kimura, Katsumata, et al., 1976

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 44100 ± 600 gas Kimura, Katsumata, et al., 1976

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 36390 ± 320 gas Mines and Thompson, 1975
Kimura, Katsumata, et al., 1976

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 33400 ± 320 gas Mines and Thompson, 1975
Kimura, Katsumata, et al., 1976

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 4110 ± 320 gas Mines and Thompson, 1975
Kimura, Katsumata, et al., 1976
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 730 ± 80 gas PE Mines and Thompson, 1975
Kimura, Katsumata, et al., 1976

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1460 ± 80 gas PE Mines and Thompson, 1975
Kimura, Katsumata, et al., 1976

Additional references: Jacox, 1994, page 319

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kimura, Katsumata, et al., 1976
Kimura, K.; Katsumata, S.; Ishiguro, T.; Hirakawa, A.Y.; Tsuboi, M., A Photoelectron Spectroscopic Study of Thioformamide, Bull. Chem. Soc. Japan, 1976, 49, 4, 937, https://doi.org/10.1246/bcsj.49.937 . [all data]

Mines and Thompson, 1975
Mines, G.W.; Thompson, H.W., The photoelectron spectra of amides, thioamides, ureas and thioureas, Spectrochim. Acta, 1975, 31, 137. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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