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CF2=PH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 PH stretch 2326.9 m gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987
2 C=P stretch 1349.5 vs gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987
3 CF2 a-stretch 1228.5 s gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987
4 CPH deform. 884.4 m gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987
5 CF2 s-stretch 729.3 m gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987
6 CF2 scissors 485.5 m gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987
7 CF2 rock 418.3 w gas IR Ohno, Kurita, et al., 1987
a 8 CPH deform. 1088.8 w gas IR Ohno, Kurita, et al., 1987
9 CF2 wag 568.0 w gas IR Ohno, Matsuura, et al., 1982
Ohno, Kurita, et al., 1987

Additional references: Jacox, 1994, page 271; Hopkinson, Kroto, et al., 1976; Kroto, 1982

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ohno, Matsuura, et al., 1982
Ohno, K.; Matsuura, H.; Kroto, H.W.; Murata, H., Chem. Lett., 1982, 981. [all data]

Ohno, Kurita, et al., 1987
Ohno, K.; Kurita, E.; Kawamura, M.; Matsuura, H., Gas-phase infrared spectra of the unstable phosphaalkenes CF2:PH, CF2:PCF3, and CH2:PC: the C:P stretching vibration and force constant, J. Am. Chem. Soc., 1987, 109, 19, 5614, https://doi.org/10.1021/ja00253a009 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Hopkinson, Kroto, et al., 1976
Hopkinson, M.J.; Kroto, H.W.; Nixon, J.F.; Simmons, N.P.C., J. Chem. Soc., 1976, Chem. Commun. 513. [all data]

Kroto, 1982
Kroto, H.W., Tilden Lecture. Semistable molecules in the laboratory and in space, Chem. Soc. Rev., 1982, 11, 4, 435, https://doi.org/10.1039/cs9821100435 . [all data]


Notes

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