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Monochlorine monoxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to ClO+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.89 ± 0.02eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
2.2775 ± 0.0013ZEKEDistelrath and Boesl, 2000B
2.2760 ± 0.0060LPESGilles, Polak, et al., 1992B
2.35 ± 0.15EIAEBaluev, Nikitin, et al., 1980From Cl2O; B
2.17 ± 0.23LPDLee, Smith, et al., 1979B
1.95 ± 0.25IMRBDotan, Albritton, et al., 1978B
>1.62 ± 0.22R-AVogt, Dreves, et al., 1977Cl- + O2 ->.; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.885 ± 0.016PIThorn, Stief, et al., 1996LL
11.08 ± 0.05EIAlekseev, Zyubina, et al., 1989LL
11.0EVALHuber and Herzberg, 1979LLK
10.95PEBulgin, Dyke, et al., 1979LLK
11.1 ± 0.1EIFisher, 1967RDSH
11.01 ± 0.01PEBulgin, Dyke, et al., 1979Vertical value; LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Distelrath and Boesl, 2000
Distelrath, V.; Boesl, U., Mass selective gas phase study of ClO, OClO, ClOO and ClAr by anion-ZEKE-photoelectron spectroscopy, Faraday Disc. Chem. Soc., 2000, 115, 161-174, https://doi.org/10.1039/a909618c . [all data]

Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C., Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-, J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352 . [all data]

Baluev, Nikitin, et al., 1980
Baluev, A.V.; Nikitin, I.M.; Fedorova, L.I.; Rossolovskii, V.Ya., Mass Spectrometric Study of Chlorine Pentafluoride Ionization by Electron Impact, Izv. Akad. Nauk SSR Ser. Khim. 487, 1980. [all data]

Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-, J. Chem. Phys., 1979, 70, 3237. [all data]

Dotan, Albritton, et al., 1978
Dotan, I.; Albritton, D.L.; Fehsenfeld, F.C.; Streit, G.E.; Ferguson, E.E., Rate constants for the reactions of O-, O2-, NO2-, CO3-, and CO4- with HCl and ClO- with NO, NO2, SO2, and CO2 at 300K, J. Chem. Phys., 1978, 68, 5414. [all data]

Vogt, Dreves, et al., 1977
Vogt, D.; Dreves, W.; Mischke, J., Energy dependence of differential cross sections in endoergic ion-molecule collision processes of negative ions, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 285. [all data]

Thorn, Stief, et al., 1996
Thorn, R.P., Jr.; Stief, L.J.; Kuo, S.-C.; Klemm, R.B., Ionization energy of Cl2O and ClO, appearance energy of ClO+(Cl2O), and heat of formation of Cl2O, J. Phys. Chem., 1996, 100, 14178. [all data]

Alekseev, Zyubina, et al., 1989
Alekseev, V.I.; Zyubina, T.S.; Zyubin, A.S.; Baluev, A.V., Mass-spectrometric and quantum-chemical investigation of thermochemical characteristics of chlorine oxides, J. Am. Chem. Soc., 1989, 2092. [all data]

Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G., Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules,, Van Nostrand Reinhold Co., 1979, ,1. [all data]

Bulgin, Dyke, et al., 1979
Bulgin, D.K.; Dyke, J.M.; Jonathan, N.; Morris, A., Vacuum ultraviolet photoelectron spectroscopy of transient species, J. Chem. Soc. Faraday Trans. 2, 1979, 75, 456. [all data]

Fisher, 1967
Fisher, I.P., Mass spectrometry study of intermediates in thermal decomposition of perchloric acid and chlorine dioxide, J. Chem. Soc. Faraday Trans., 1967, 63, 684. [all data]


Notes

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