Nitrosyl iodide
- Formula: INO
- Molecular weight: 156.9106
- IUPAC Standard InChI: InChI=1S/INO/c1-2-3
- IUPAC Standard InChIKey: VBAXOVGEFYCYMW-UHFFFAOYSA-N
- CAS Registry Number: 58585-94-7
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 112.13 | kJ/mol | Review | Chase, 1998 | Data last reviewed in December, 1966 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 282.96 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1966 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. - 600. | 600. - 6000. |
|---|---|---|
| A | 48.53398 | 54.11251 |
| B | -7.517184 | 2.711024 |
| C | 34.58423 | -0.624152 |
| D | -22.30980 | 0.047665 |
| E | -0.170642 | -1.645384 |
| F | 97.16127 | 91.30952 |
| G | 341.6353 | 340.9977 |
| H | 112.1312 | 112.1312 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in December, 1966 | Data last reviewed in December, 1966 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: B
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 42000 | gas | B-X | 223 | 310 | van den Bergh and Troe, 1976 | ||
| Basco and Hunt, 1978 | |||||||
| Forte, Hippler, et al., 1981 | |||||||
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 23800 | gas | A-X | 390 | 470 | Porter, Szabo, et al., 1962 | ||
| van den Bergh and Troe, 1976 | |||||||
| Basco and Hunt, 1978 | |||||||
| Forte, Hippler, et al., 1981 | |||||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 1 | NO stretch | 1785 | gas | IR | Barnes, Becker, et al., 1991 | |
| 1 | NO stretch | 1809 | Ar | IR | Feuerhahn, Hilbig, et al., 1978 | ||
| 1 | NO stretch | 1806 | Kr | IR | Fried and Mathews, 1977 | ||
| 2 | Bend | 216 | Ar | IR | Feuerhahn, Hilbig, et al., 1978 | ||
| 3 | NI stretch | 470 | Ar | IR | Feuerhahn, Hilbig, et al., 1978 | ||
| 3 | NI stretch | 468 | Kr | IR | Fried and Mathews, 1977 | ||
Additional references: Jacox, 1994, page 102
Notes
| x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
van den Bergh and Troe, 1976
van den Bergh, H.; Troe, J.,
Kinetic and thermodynamic properties of INO and INO2 intermediate complexes in iodine recombination,
J. Chem. Phys., 1976, 64, 2, 736, https://doi.org/10.1063/1.432220
. [all data]
Basco and Hunt, 1978
Basco, N.; Hunt, J.E.,
The recombination of iodine atoms in the presence of nitric oxide,
Int. J. Chem. Kinet., 1978, 10, 7, 733, https://doi.org/10.1002/kin.550100707
. [all data]
Forte, Hippler, et al., 1981
Forte, E.; Hippler, H.; van den Bergh, H.,
INO thermodynamic properties and ultraviolet spectrum,
Int. J. Chem. Kinet., 1981, 13, 12, 1227, https://doi.org/10.1002/kin.550131203
. [all data]
Porter, Szabo, et al., 1962
Porter, G.; Szabo, Z.G.; Townsend, M.G.,
The Recombination of Atoms V. Iodine Atom Recombination in Nitric Oxide,
Proc. Roy. Soc. (London) A270, 1962, 270, 1343, 493, https://doi.org/10.1098/rspa.1962.0239
. [all data]
Barnes, Becker, et al., 1991
Barnes, I.; Becker, K.H.; Starcke, J.,
Fourier-transform IR spectroscopic observation of gaseous nitrosyl iodine, nitryl iodine, and iodine nitrate,
J. Phys. Chem., 1991, 95, 24, 9736, https://doi.org/10.1021/j100177a026
. [all data]
Feuerhahn, Hilbig, et al., 1978
Feuerhahn, M.; Hilbig, W.; Minkwitz, R.; Engelhardt, U.,
Spectrochim. Acta, 1978, 34A, 1065. [all data]
Fried and Mathews, 1977
Fried, A.; Mathews, C.W.,
The resonance fluorescence of BO2 excited by a pulsed dye-laser,
Chem. Phys. Lett., 1977, 52, 2, 363, https://doi.org/10.1016/0009-2614(77)80560-5
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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