Dimanganese decacarbonyl

• Formula: C₁₀Mn₂O₁₀
• Molecular weight: 389.9771
• IUPAC Standard InChI: InChI=1S/10CO.2Mn/c10*1-2;; Copy

  
• IUPAC Standard InChIKey: QFEOTYVTTQCYAZ-UHFFFAOYSA-N Copy
• CAS Registry Number: 10170-69-1
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Mn2(CO)10; Manganese carbonyl; Manganese, decacarbonyldi-,; Decacarbonyldimanganese; Manganese carbonyl (Mn2(CO)10); Manganese, decacarbonyldi-, (Mn-Mn)
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
  • Switch to calorie-based units

Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Enthalpy of vaporization

Enthalpy of sublimation

References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Good, Fairbrother, et al., 1958
Good, W.D.; Fairbrother, D.M.; Waddington, Guy, Manganese Carbonyl: Heat of Formation by Rotating-Bomb Calorimetry, J. Phys. Chem., 1958, 62, 7, 853-856, https://doi.org/10.1021/j150565a021 . [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Behrens, 1976
Behrens, R.G., J. Organometal. Chem., 1976, 121, C63. [all data]

Cotton and Monchamp, 1960
Cotton, F.A.; Monchamp, R.R., J. Chem. Soc., 1960, 533.. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Notes

Go To: Top, Phase change data, References

• Symbols used in this document:
  

  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.