Ruthenium monoxide
- Formula: ORu
- Molecular weight: 117.07
- IUPAC Standard InChI: InChI=1S/O.Ru/q-2;+2
- IUPAC Standard InChIKey: KZECJIQUDMPFJV-UHFFFAOYSA-N
- CAS Registry Number: 12143-05-4
- Chemical structure:
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Constants of diatomic molecules
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through May, 1975
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Additional unclassified emission bands in the region 15500 - 17200 cm-1. | ||||||||||||
| ↳Scullman and Thelin, 1975 | ||||||||||||
| B3 | a3 + 18121.4 | 792.9 H | 4.1 | 0.3818 | 0.0025 | 4E-7 | 1.7871 | B3 → A3 1 R | 18086.2 Z | |||
| ↳Raziunas, Macur, et al., 1965; missing citation | ||||||||||||
| B2 (Ω=3) | a2 + 18101 | [783] H | [0.382] 2 | [6E-7] 2 | [1.787] | B2 → A2 1 R | 18065.1 Z | |||||
| ↳Raziunas, Macur, et al., 1965; missing citation | ||||||||||||
| B1 | [(0.384)] | [(1.78)] | B1 → A1 1 R | 18024 Z | ||||||||
| ↳Raziunas, Macur, et al., 1965; Scullman and Thelin, 1975 | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| A3 | a3 3 | 863.5 H | 4.6 | 0.4137 | 0.0028 | 3E-7 | 1.7168 | |||||
| A2 (Ω=3) | a2 3 | [855] H | [0.4144] 4 | [3.9E-7] | [1.7154] | |||||||
| A1 | a1 3 | [(0.414)] | [(1.72)] | |||||||||
Notes
| 1 | R and P branches only. |
| 2 | B1 = 0.381, D1= 9E-7. Perturbations. |
| 3 | Relative position of these three states unknown. |
| 4 | B1 = 0.413. |
| 5 | Thermochemical value (mass-spectrometry) Norman, Staley, et al., 1968. |
References
Go To: Top, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Scullman and Thelin, 1975
Scullman, R.; Thelin, B.,
The emission spectrum of RuO between 5000 and 6800 Å,
J. Mol. Spectrosc., 1975, 56, 64. [all data]
Raziunas, Macur, et al., 1965
Raziunas, V.; Macur, G.; Katz, S.,
Emission spectrum and thermodynamic properties of ruthenium monoxide,
J. Chem. Phys., 1965, 43, 1010. [all data]
Norman, Staley, et al., 1968
Norman, J.H.; Staley, H.G.; Bell, W.E.,
Mass spectrometric study of the noble metal oxides. Ruthenium-oxygen system,
Advan. Chem. Ser., 1968, 72, 101. [all data]
Notes
Go To: Top, Constants of diatomic molecules, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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