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8-Hydroxyquinoline

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas1.6 ± 0.41kcal/molCcbRibeiro Da Silva, Monte, et al., 1989Author was aware that data differs from previously reported values
Deltafgas6.60 ± 0.62kcal/molCcrSakiyama, Nakano, et al., 1975 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-19.8 ± 0.36kcal/molCcbRibeiro Da Silva, Monte, et al., 1989Author was aware that data differs from previously reported values
Deltafsolid-19.4 ± 0.48kcal/molCcrSakiyama, Nakano, et al., 1975 
Quantity Value Units Method Reference Comment
Deltacsolid-1065.7 ± 0.2kcal/molCcbRibeiro Da Silva, Monte, et al., 1989Author was aware that data differs from previously reported values
Deltacsolid-1066.15 ± 0.38kcal/molCcrSakiyama, Nakano, et al., 1975 
Deltacsolid-1067.8kcal/molCcbWood and Jones, 1963 
Deltacsolid-1064.9 ± 0.2kcal/molCcbSullivan and Hunt, 1949 
Deltacsolid-1065.3 ± 2.0kcal/molCcbSullivan, Kibler, et al., 1948 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus347.65KN/AManske, Ledingham, et al., 1949Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltasub23. ± 4.kcal/molAVGN/AAverage of 6 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
540.20.989Aldrich Chemical Company Inc., 1990BS

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
26.00 ± 0.41308. - 328.MEHorton and Wendlandt, 1963See also Cox and Pilcher, 1970 and Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
9.63345.7ACWANG, TAN, et al., 2008AC
5.28346.8N/AZorel, Costalonga, et al., 2001AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 290917

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Lang (editor), 1961
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 19765
Instrument SF-4
Melting point 74

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-1011326.3Ferchichi and Messadi, 19944. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 30. C; Tend: 250. C
CapillaryOV-1011348.9Ferchichi and Messadi, 19944. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 30. C; Tend: 250. C
CapillaryDB-51358.Rostad and Pereira, 198630. m/0.26 mm/0.25 «mu»m, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryUltra-11339.Du, Clery, et al., 200850. m/0.20 mm/0.33 «mu»m, Helium, 2. K/min, 280. C @ 20. min; Tstart: 50. C
CapillaryHP-51362.Du, Clery, et al., 200850. m/0.20 mm/0.33 «mu»m, Helium, 10. K/min, 280. C @ 8.5 min; Tstart: 50. C
CapillaryUltra-11312.Okumura, 199125. m/0.32 mm/0.25 «mu»m, He, 3. K/min; Tstart: 80. C; Tend: 260. C

Normal alkane RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-Innowax2153.Du, Clery, et al., 200850. m/0.20 mm/0.33 «mu»m, Helium, 10. K/min, 250. C @ 6. min; Tstart: 50. C

Lee's RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-5232.24Rostad and Pereira, 198630. m/0.26 mm/0.25 «mu»m, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro Da Silva, Monte, et al., 1989
Ribeiro Da Silva, M.A.V.; Monte, M.J.S.; Matos, M.A.R., Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 8-hydroxyquinoline, 5-nitro-8-hydroxyquinoline, and 2-methyl-8-hydroxyquinoline, J. Chem. Thermodyn., 1989, 21, 159-166. [all data]

Sakiyama, Nakano, et al., 1975
Sakiyama, M.; Nakano, T.; Seki, S., Enthalpies of combustion of organic compounds. I. 8-Quinolinol., Bull. Chem. Soc. Jpn., 1975, 48, 1705-1708. [all data]

Wood and Jones, 1963
Wood, J.L.; Jones, M.M., Heats of formation and coordinate bond energies of some nickel(II) chelates, J. Phys. Chem., 1963, 67, 1049-1051. [all data]

Sullivan and Hunt, 1949
Sullivan, M.V.; Hunt, H., Heats of combustion. IV. The heats of combustion of five aromatic amines, J. Phys. Chem., 1949, 53, 497-500. [all data]

Sullivan, Kibler, et al., 1948
Sullivan, M.V.; Kibler, G.M.; Hunt, H., Heats of combustion of nitrogen containing compounds, Rpt. Tech. Memo. PUR-3 for USN Project SQUID Contract N6ori-104, Task Order No. 1 Designation No. NR 22 042 by Purdue University, Lafayette, IN, 1948, 1-46. [all data]

Manske, Ledingham, et al., 1949
Manske, R.H.F.; Ledingham, A.E.; Ashford, W.R., The preparation of quinolins by a modified Skraup reaction., Can. J. Res., 1949, 27F, 359. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Horton and Wendlandt, 1963
Horton, G.R.; Wendlandt, W.W., The heats of dissociation of the 8-quinolinol and substituted 8-quinolinol metal chelates of uranium (VI), thorium (IV) and scandium (III), J. Inorg. Nucl. Chem., 1963, 25, 241-245. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

WANG, TAN, et al., 2008
WANG, Shao-Xu; TAN, Zhi-Cheng; LI, Yan-Sheng; TONG, Bo; LI, Ying; SHI, Quan; ZHANG, Jing-Nan, Thermodynamic Study of 8-Hydroxyquinoline by Adiabatic Calorimetry and Thermal Analysis, Chin. J. Chem., 2008, 26, 11, 2016-2020, https://doi.org/10.1002/cjoc.200890360 . [all data]

Zorel, Costalonga, et al., 2001
Zorel, H.E., Jr.; Costalonga, A.G.C.; Crespi, M.S.; Ribiero, C.A., Quim. Nova, 2001, 24, 5, 599. [all data]

Lang (editor), 1961
Lang (editor), L., Absorption Spectra in the Ultraviolet and Visible Region, 1961, 2, 373. [all data]

Ferchichi and Messadi, 1994
Ferchichi, L.; Messadi, D., Simulations de la rétention et de l'effecacité de colonne en chromatographie en phase gazeuse à température programmée: théorie et application, Analusis, 1994, 22, 392-399. [all data]

Rostad and Pereira, 1986
Rostad, C.E.; Pereira, W.E., Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 6, 328-334, https://doi.org/10.1002/jhrc.1240090603 . [all data]

Du, Clery, et al., 2008
Du, Z.; Clery, R.; Hammond, C.J., Volatile organic nitrogen-containing constituents in ambrette seed Abelmoschus moschatus Medik (Malvaceae), J. Agric. Food Chem., 2008, 56, 16, 7388-7392, https://doi.org/10.1021/jf800958d . [all data]

Okumura, 1991
Okumura, T., retention indices of environmental chemicals on methyl silicone capillary column, Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333 . [all data]


Notes

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