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Methane, triiodo-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid181.1 ± 1.0kJ/molCcrCarson, Laye, et al., 1993ALS
Quantity Value Units Method Reference Comment
Deltacsolid-717.5 ± 0.6kJ/molCcrCarson, Laye, et al., 1993ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
157.5298.15Carson, Laye, et al., 1993DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus394.25KN/AVanderwerf, Davidson, et al., 1948Uncertainty assigned by TRC = 0.4 K; TRC
Tfus398.0KN/AVan de Vloed, 1939Uncertainty assigned by TRC = 0.6 K; TRC
Tfus391.25KN/AFruhwirth and Mayer-Pitsch, 1937Uncertainty assigned by TRC = 0.5 K; TRC
Tfus392.15KN/AEarp and Glasstone, 1935Uncertainty assigned by TRC = 1.5 K; TRC
Tfus392.KN/ABuechner, 1906Uncertainty assigned by TRC = 2. K; TRC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Reference Comment
69.9323.Nitta and Seki, 1943Based on data from 308. - 365. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-8704
NIST MS number 228071

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carson, Laye, et al., 1993
Carson, A.S.; Laye, P.G.; Pedley, J.B.; Welsby, A.M., The enthalpies of formation iodomethane, diiodomethane, triiodomethane, and tetraiodomethane by rotating combustion calorimetry, J. Chem. Thermodyn., 1993, 25, 261-269. [all data]

Vanderwerf, Davidson, et al., 1948
Vanderwerf, C.A.; Davidson, A.W.; Michaelis, C.I., Compound Formation Betwee 2,6-Lutidine and Polyhalogenated Methanes, J. Am. Chem. Soc., 1948, 70, 908. [all data]

Van de Vloed, 1939
Van de Vloed, A., Bull. Soc. Chim. Belg., 1939, 48, 229. [all data]

Fruhwirth and Mayer-Pitsch, 1937
Fruhwirth, V.O.; Mayer-Pitsch, E., The Dielectric Investigation of Compound Formation in Binary Mixtures, Especially in the Diethyl Ether + Chlorform, Acetamide + Phenol and Iodoform + Quinoline Systems, Z. Elektrochem., 1937, 43, 304. [all data]

Earp and Glasstone, 1935
Earp, D.P.; Glasstone, S., Dielectric polarisation and molecular-compound formation in solution, J. Chem. Soc., 1935, 1935, 1709. [all data]

Buechner, 1906
Buechner, E.H., Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1906, 54, 665. [all data]

Nitta and Seki, 1943
Nitta, I.; Seki, S., J. Chem. Soc. Jpn., 1943, 64, 475. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References