vinylamine

• Formula: C₂H₅N
• Molecular weight: 43.0678
• IUPAC Standard InChI: InChI=1S/C2H5N/c1-2-3/h2H,1,3H2 Copy

  
• IUPAC Standard InChIKey: UYMKPFRHYYNDTL-UHFFFAOYSA-N Copy
• CAS Registry Number: 593-67-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Ethenamine
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• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

View reactions leading to C₂H₅N⁺ (ion structure unspecified)

Ionization energy determinations

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 375; Jacox, 1998, page 336; Jacox, 2003, page 352; Lovas, Clark, et al., 1975; Brown, Godfrey, et al., 1987; McNaughton and Robertson, 1994

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Takhistov and Ponomarev, 1994
Takhistov, V.V.; Ponomarev, D.A., Isodesmic reactions and thermochemistry of ions, Org. Mass Spectrom., 1994, 29, 395. [all data]

Albercht, Allan, et al., 1984
Albercht, B.; Allan, M.; Haselbach, E.; Neuhaus, L.; Carrupt, P.-A., 27. Molecular ions of transient species: Vinylamine-cation, Helv. Chim. Acta, 1984, 67, 220. [all data]

Gonbeau, Lacombe, et al., 1988
Gonbeau, D.; Lacombe, S.; Lasnes, M.; Ripoll, J.; Pfister-Guillouzo, G., Ethenylphosphine. Synthesis by flash-vacuum thermolysis and characterization by photoelectron spectroscopy, J. Am. Chem. Soc., 1988, 110, 2730. [all data]

Hamada, Hashiguchi, et al., 1984
Hamada, Y.; Hashiguchi, K.; Tsuboi, M.; Koga, Y.; Kondo, S., Pyrolysis of amines: Infrared spectrum of vinylamine, J. Mol. Spectrosc., 1984, 105, 1, 93, https://doi.org/10.1016/0022-2852(84)90106-1 . [all data]

Hamada, Sato, et al., 1987
Hamada, Y.; Sato, N.; Tsuboi, M., Amino wagging and torsion vibrations of vinylamine, J. Mol. Spectrosc., 1987, 124, 1, 172, https://doi.org/10.1016/0022-2852(87)90130-5 . [all data]

Brown, Godfrey, et al., 1990
Brown, R.D.; Godfrey, P.D.; Kleibomer, B.; Pierlot, A.P.; McNaughton, D., Submillimeter-wave spectrum, far-infrared spectrum, and inversion potential of vinylamine, J. Mol. Spectrosc., 1990, 142, 2, 195, https://doi.org/10.1016/0022-2852(90)90177-R . [all data]

McNaughton and Evans, 1999
McNaughton, D.; Evans, C.J., The High-Resolution FTIR Far-Infrared Spectrum of Vinylamine, J. Mol. Spectrosc., 1999, 196, 2, 274, https://doi.org/10.1006/jmsp.1999.7861 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Lovas, Clark, et al., 1975
Lovas, F.J.; Clark, F.O.; Tiemann, E., Pyrolysis of ethylamine. I. Microwave spectrum and molecular constants of vinylamine, J. Chem. Phys., 1975, 62, 5, 1925, https://doi.org/10.1063/1.430679 . [all data]

Brown, Godfrey, et al., 1987
Brown, R.D.; Godfrey, P.D.; Kleibomer, B., The inversion-torsion motion in vinylamine, J. Mol. Spectrosc., 1987, 124, 1, 21, https://doi.org/10.1016/0022-2852(87)90117-2 . [all data]

McNaughton and Robertson, 1994
McNaughton, D.; Robertson, E.G., The Far-Infrared Inversion Transition of Vinylamine, J. Mol. Spectrosc., 1994, 163, 1, 80, https://doi.org/10.1006/jmsp.1994.1009 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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