Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Bicyclo[2.2.0]hexa-2,5-diene,1,2,3,4,5,6-hexafluoro-


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.4 ± 0.1EIPraet, Hubin-Franskin, et al., 1977LLK
10.08 ± 0.05PEDelwiche and Praet, 1975LLK
10.4PEBieri, Heilbronner, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CF+15.6 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977LLK
CF3+15. ± 0.4CF3EIPraet, Hubin-Franskin, et al., 1977LLK
CF3+22.7 ± 0.4CF+C3+CF2EIPraet, Hubin-Franskin, et al., 1977LLK
CF3+19.4 ± 0.4CF+C4F2EIPraet, Hubin-Franskin, et al., 1977LLK
CF3+16.5 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977LLK
C3F+22.4 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977LLK
C3F2+13.5 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977LLK
C3F3+15.6 ± 0.4C3F3EIPraet, Hubin-Franskin, et al., 1977LLK
C3F3+19.6 ± 0.4CF+C2F2EIPraet, Hubin-Franskin, et al., 1977LLK
C3F3+15.0 ± 0.2?EIPraet, Hubin-Franskin, et al., 1977LLK
C4F2+16.0 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977LLK
C4F3+16.8 ± 0.2?EIPraet, Hubin-Franskin, et al., 1977LLK
C5F2+25. ± 0.4F+CF3EIPraet, Hubin-Franskin, et al., 1977LLK
C5F2+17.8 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977LLK
C5F2+25. ± 0.4F2+CF2EIPraet, Hubin-Franskin, et al., 1977LLK
C5F3+13.8 ± 0.1?EIPraet, Hubin-Franskin, et al., 1977LLK
C5F3+17.5 ± 0.4F+CF2EIPraet, Hubin-Franskin, et al., 1977LLK
C5F3+15. ± 0.4CF3EIPraet, Hubin-Franskin, et al., 1977LLK
C5F4+13.8 ± 0.2?EIPraet, Hubin-Franskin, et al., 1977LLK
C5F4+14.8 ± 0.4CF2EIPraet, Hubin-Franskin, et al., 1977LLK
C5F5+18.5 ± 0.2?EIPraet, Hubin-Franskin, et al., 1977LLK
C6F5+14.6 ± 0.2?EIPraet, Hubin-Franskin, et al., 1977LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Praet, Hubin-Franskin, et al., 1977
Praet, M-Th.; Hubin-Franskin, M.J.; Delwiche, J.P.; Schoos, R., Ionization and dissociation of C6F6 isomers under electron impact, Org. Mass Spectrom., 1977, 12, 297. [all data]

Delwiche and Praet, 1975
Delwiche, J.P.; Praet, M.Th., Spectre de photoelectrons He(I) de l'hexafluorobicyclo-[2.2.0]- hexadiene-2,5, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 317. [all data]

Bieri, Heilbronner, et al., 1976
Bieri, G.; Heilbronner, E.; Kobayashi, T.; Schmelzer, A.; Goldstein, M.J.; Leight, R.S.; Lipton, M.S., 286. Dewar benzene some of its derivatives. A photoelectron spectroscopic analysis, Helv. Chim. Acta, 1976, 59, 2657. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References