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2-Methyl-bicyclo[2.2.2]-oct-2-ene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-4.45 ± 0.55kcal/molCmKozina, Bychikhina, et al., 1974 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-14.81 ± 0.52kcal/molCmKozina, Bychikhina, et al., 1974 
Quantity Value Units Method Reference Comment
Deltacliquid-1309.86 ± 0.51kcal/molCmKozina, Bychikhina, et al., 1974Corresponding «DELTA»fliquid = -14.81 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltavap10.36 ± 0.18kcal/molVKozina, Bychikhina, et al., 1974ALS
Deltavap10.4kcal/molN/AKozina, Bychikhina, et al., 1974DRB
Deltavap10.4 ± 0.1kcal/molEBVarushchenko, Druzhimina, et al., 1974See also Kozina, Bychikhina, et al., 1974, 2.; AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
9.61378.AStephenson and Malanowski, 1987Based on data from 363. - 402. K.; AC

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Bychikhina, et al., 1974
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.; Kalinichenko, A.N.; Bobyleva, A.A.; Belikova, N.A.; Plate, A.F., Enthalpies of combustion and formation of 2-methylenebicyclo-[2,2,2]octane and 2-methylbicylo-[2,2,2]oct-2-ene, Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 1226-1227. [all data]

Varushchenko, Druzhimina, et al., 1974
Varushchenko, R.M.; Druzhimina, A.I.; Kovner, O.Y.; Mil'vitskaya, E.M.; Bobyleva, A.A.; Belikova, N.A.; Gal'chenko, G.L., Russ. J. Phys. Chem., 1974, 48, 1121. [all data]

Kozina, Bychikhina, et al., 1974, 2
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.; Kalinichenko, A.N.; Bobyleva, A.A.; Belikova, N.A.; Plate, A.F., Zh. Fiz. Khim., 1974, 48, 2075. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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