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Propanal

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil322. ± 2.KAVGN/AAverage of 39 out of 41 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus180. ± 20.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple171.32KN/AVasil'ev and Petrov, 1984Uncertainty assigned by TRC = 0.01 K; TRC
Ttriple171.15KN/AKorkhov and Vasil'ev, 1977Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple171.32KN/AKorkhov and Vasil'ev, 1977Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Tc600. ± 200.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Pc52.60barN/AGude and Teja, 1994Uncertainty assigned by TRC = 0.60 bar; by the flow method; TRC
Pc52.70barN/AGude and Teja, 1994Uncertainty assigned by TRC = 1.00 bar; by sealed ampule; TRC
Pc52.70barN/ATeja and Rosenthal, 1990Uncertainty assigned by TRC = 1.00 bar; TRC
Pc68.6983barN/ABougard and Jadot, 1977source of data not clear; TRC
Pc68.6984barN/ASvoboda, Vesely, et al., 1977Uncertainty assigned by TRC = 2.026 bar; TRC
Quantity Value Units Method Reference Comment
rhoc4.91mol/lN/AAnselme and Teja, 1990Uncertainty assigned by TRC = 0.09 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap29.7 ± 0.3kJ/molAVGN/AAverage of 11 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
28.31321.1N/AMajer and Svoboda, 1985 
28.320321.08N/AKorkhov and Vasil'ev, 1977, 2DH
30.3305.AStephenson and Malanowski, 1987Based on data from 290. - 322. K. See also Dykyj, 1970.; AC
31.9265.EBStephenson and Malanowski, 1987Based on data from 250. - 330. K. See also Smith and Bonner, 1951.; AC
31.5278.N/AKim and Kim, 1977Based on data from 263. - 373. K.; AC
30.5301.N/AAmbrose and Sprake, 1974Based on data from 286. - 321. K.; AC
28.3321.N/ACounsell and Lee, 1972AC
29.4303.N/ACounsell and Lee, 1972AC
30.3286.N/ACounsell and Lee, 1972AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
286. - 321.44.480.2676496.2Majer and Svoboda, 1985 

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.590171.32Korkhov and Vasil'ev, 1977, 2DH
8.59171.3Domalski and Hearing, 1996AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasil'ev and Petrov, 1984
Vasil'ev, I.A.; Petrov, V.M., Thermodynamic Properties of Oxygen-containing Organic Compounds, Handbook, Soedinenii: Khimya, Leningrad, p 240, 1984. [all data]

Korkhov and Vasil'ev, 1977
Korkhov, A.D.; Vasil'ev, I.A., Heat capacity and thermodynamic functions of propionaldehyde at low temperatures., Termodin. Org. Soedin., 1977, No. 6, 34. [all data]

Gude and Teja, 1994
Gude, M.T.; Teja, A.S., The Critical Properties of Several n-Alkanals, Tetralin and NMP, Experimental Results for DIPPR 1990-91 Projects on Phase Equilibria and Pure Component Properties, 1994, 1994, DIPPR Data Series No. 2, p.174-83. [all data]

Teja and Rosenthal, 1990
Teja, A.S.; Rosenthal, D.J., The Critical Pressures and Temperatures of Twelve Substances Using A Low Residence Time Flow Apparatus, AIChE Symp. Ser., 1990, 86, 279, 133-7. [all data]

Bougard and Jadot, 1977
Bougard, J.; Jadot, R., Isothermal Vapor-Liquid Equilibria for the System 1,2-Dichloropropane- Propanal, J. Chem. Eng. Data, 1977, 22, 88. [all data]

Svoboda, Vesely, et al., 1977
Svoboda, V.; Vesely, F.; Holub, R.; Pick, J., Heats of vaporization of alkyl acetates and propionates, Collect. Czech. Chem. Commun., 1977, 42, 943-51. [all data]

Anselme and Teja, 1990
Anselme, M.J.; Teja, A.S., The critical properties of rapidly reacting substances, AIChE Symp. Ser., 1990, 86, 279, 128-32. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Korkhov and Vasil'ev, 1977, 2
Korkhov, A.D.; Vasil'ev, I.A., Heat capacity and thermodynamic functions of propanal at low temperatures, Termodin. Org. Soedin., 1977, (6), 34-37. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Smith and Bonner, 1951
Smith, Thomas E.; Bonner, Robert F., Acetaldehyde, Propionaldehyde, and n-Butyraldehyde, Ind. Eng. Chem., 1951, 43, 5, 1169-1173, https://doi.org/10.1021/ie50497a049 . [all data]

Kim and Kim, 1977
Kim, B.C.; Kim, D.H., Hwahak Kwa Hwahak Kongop, 1977, 20, 232. [all data]

Ambrose and Sprake, 1974
Ambrose, D.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds 32. Vapour pressure and second virial coefficient of propanal, The Journal of Chemical Thermodynamics, 1974, 6, 5, 453-456, https://doi.org/10.1016/0021-9614(74)90006-8 . [all data]

Counsell and Lee, 1972
Counsell, J.F.; Lee, D.A., Thermodynamic properties of organic oxygen compounds 30. Vapour heat capacity and enthalpy of vaporization of propanal, The Journal of Chemical Thermodynamics, 1972, 4, 6, 915-917, https://doi.org/10.1016/0021-9614(72)90013-4 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Phase change data, References