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1,3-Dioxolan-2-one

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-120.2 ± 1.0kcal/molCcbChoi and Joncich, 1971Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -144.43 kcal/mol; Pedley's value is off by 24.20kcal/mol; ALS

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
19.5298.15Vasilev I.A., 1984GT
19.6300.
25.07400.
29.76500.
33.58600.
36.69700.
39.22800.
41.35900.
43.121000.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-163.20 ± 0.50kcal/molCcbChoi and Joncich, 1971Pedley's value is off by 24.20kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-255.58 ± 0.50kcal/molCcbChoi and Joncich, 1971Pedley's value is off by 24.20kcal/mol; Corresponding «DELTA»fliquid = -163.20 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Deltafsolid-141.2kcal/molCcbVogdanis, Martens, et al., 1990ALS
Deltafsolid-140.1 ± 0.90kcal/molCcbCalhoun, 1983ALS
Deltafsolid-139.00 ± 0.09kcal/molCcbVasil'eva, Zhil'tosova, et al., 1972ALS
Quantity Value Units Method Reference Comment
Deltacsolid-277.58kcal/molCcbVogdanis, Martens, et al., 1990Corresponding «DELTA»fsolid = -141.2 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-278.65 ± 0.89kcal/molCcbCalhoun, 1983Corresponding «DELTA»fsolid = -140.13 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-279.78 ± 0.09kcal/molCcbVasil'eva, Zhil'tosova, et al., 1972Corresponding «DELTA»fsolid = -139.00 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-279.9516kcal/molCcbSilvestro and Lenchitz, 1961Corresponding «DELTA»fsolid = -138.8319 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar31.678cal/mol*KN/AVasil'ev and Korkhov, 1974DH
solid,1 bar31.678cal/mol*KN/AVasil'ev and Korkhov, 1973Extrapolation below 52 K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
32.00323.15Peppel, 1958DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
28.069298.15Vasil'ev and Korkhov, 1974T = 52 to 340 K. Cp(liq) = 88.977 + 0.1586T J/mol*K (309 to 340 K).; DH
28.069298.15Vasil'ev and Korkhov, 1973T = 52 to 310 K. Full data deposited in VINITI, No. 326-73, 21 June 1973.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J., Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation, J. Chem. Eng. Data, 1971, 16, 87-90. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Vasilev I.A., 1984
Vasilev I.A., Thermodynamic Properties of Oxygen-Containing Organic Compounds. Khimiya, Leningrad, 1984. [all data]

Vogdanis, Martens, et al., 1990
Vogdanis, L.; Martens, B.; Uchtmann, H.; Hensel, F.; Heitz, W., Synthetic and thermodynamic investigations in the polymerization of ethylene carbonate, Makromol. Chem., 1990, 191, 456-472. [all data]

Calhoun, 1983
Calhoun, W.L., Enthalpies of combustion and formation of ethylene carbonate, J. Chem. Eng. Data, 1983, 28, 146-148. [all data]

Vasil'eva, Zhil'tosova, et al., 1972
Vasil'eva, T.F.; Zhil'tosova, E.N.; Vvedenski, A.A., Enthalpies of combustion of alkylene carbonates, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 316. [all data]

Silvestro and Lenchitz, 1961
Silvestro, G.; Lenchitz, C., Heat of combustion of ethylene carbonate, J. Phys. Chem., 1961, 65, 694-695. [all data]

Vasil'ev and Korkhov, 1974
Vasil'ev, I.A.; Korkhov, A.D., Thermodynamic properties of alkylene carbonates at low temperatures, Tr. Khim. Khim. Tekhnol., Gor'kii, 1974, 36, 103-105. [all data]

Vasil'ev and Korkhov, 1973
Vasil'ev, I.A.; Korkhov, A.D., The heat capacities and enthalpies of fusion and the thermodynamic properties of solid and liquid ethylene carbonate, Zhur. Fiz. Khim., 1973, 47, 2710. [all data]

Peppel, 1958
Peppel, W.J., Preparation and properties of the alkylene carbonates, Ind. Eng. Chem., 1958, 50, 767-770. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References