Tetra-N-butylammonium bromide

• Formula: C₁₆H₃₆BrN
• Molecular weight: 322.368
• IUPAC Standard InChI: InChI=1S/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1 Copy

  
• IUPAC Standard InChIKey: JRMUNVKIHCOMHV-UHFFFAOYSA-M Copy
• CAS Registry Number: 1643-19-2
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Tetrabutylammonium bromide; TBAB; 1-Butanaminium, N,N,N-tributyl-, bromide
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

Entropy of fusion

Enthalpy of phase transition

Entropy of phase transition

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nagano, Mizuno, et al., 1991
Nagano, Y.; Mizuno, H.; Sakiyama, M.; Fujiwara, T.; Kondo, Y., Hydration enthalpy of tetra-n-butylammonium ion, J. Phys. Chem., 1991, 95, 2536-2540. [all data]

Burns and Verrall, 1974
Burns, I.A.; Verrall, R.E., Thermodynamics of tetralkyl- and bis-tetraalkylammonium bromides. II. Heat capacities of solid state from 273 to 373 K, Thermochim. Acta, 1974, 9, 277-287. [all data]

de Visser and Somsen, 1973
de Visser, C.; Somsen, G., Enthalpies of solution and heat capacities of tetra-n-butylammonium bromide in several solvents from 278-328 K, J. Chem. Thermodynam., 1973, 5, 147-152. [all data]

Burns and Verrall, 1974, 2
Burns, J.A.; Verrall, R.E., Thermodynamics of tetraalkyl- and bis-tetraalkylammonium bromides. II. Heat capacities of solid state from 273 to 373 K., Thermochim. Acta, 1974, 9, 277. [all data]

Coker, Ambrose, et al., 1970
Coker, T.G.; Ambrose, J.; Janz, G.J., Fusion properties of some ionic quaternary ammonium compounds., J. Am. Chem. Soc., 1970, 92, 5293. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  Tfus	Fusion (melting) point
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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