PdCO
- Formula: COPd
- Molecular weight: 134.43
- CAS Registry Number: 41772-86-5
- Information on this page:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | CO stretch | 2140 ± 60 | gas | PE | Klopcic, Moravec, et al., 1999 | |
| 1 | CO stretch | 2056.4 | Ne | IR | Liang, Zhou, et al., 2000 | ||
| 1 | CO stretch | 2044.2 | Ar | IR | Kundig, Moskovits, et al., 1972 Darling and Ogden, 1973 Tremblay and Manceron, 1999 | ||
| 1 | CO stretch | 2045 | Kr | IR | Darling and Ogden, 1973 | ||
| Π | 2 | Bend | 615.7 | w | Ar | IR | Tremblay and Manceron, 1999 |
| Σ+ | 3 | PdC stretch | 350 ± 40 | gas | PE | Klopcic, Moravec, et al., 1999 | |
| 3 | PdC stretch | 472.0 | w | Ar | IR | Tremblay and Manceron, 1999 | |
Additional references: Jacox, 1998, page 167; Jacox, 2003, page 67; Walker, Hui, et al., 2002
Notes
| w | Weak |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Klopcic, Moravec, et al., 1999
Klopcic, S.A.; Moravec, V.D.; Jarrold, C.C.,
Anion photoelectron spectroscopy of PdCO[sup -] and PdCN: Reactivity of Pd[sup -],
J. Chem. Phys., 1999, 110, 18, 8986, https://doi.org/10.1063/1.478817
. [all data]
Liang, Zhou, et al., 2000
Liang, B.; Zhou, M.; Andrews, L.,
Reactions of Laser-Ablated Ni, Pd, and Pt Atoms with Carbon Monoxide: Matrix Infrared Spectra and Density Functional Calculations on M(CO),
J. Phys. Chem. A, 2000, 104, 17, 3905, https://doi.org/10.1021/jp993646q
. [all data]
Kundig, Moskovits, et al., 1972
Kundig, E.P.; Moskovits, M.; Ozin, G.A.,
Intermediate Binary Carbonyls of Palladium Pd(CO),
Can. J. Chem., 1972, 50, 22, 3587, https://doi.org/10.1139/v72-573
. [all data]
Darling and Ogden, 1973
Darling, J.H.; Ogden, J.S.,
J. Chem. Soc., 1973, Dalton Trans. 1079. [all data]
Tremblay and Manceron, 1999
Tremblay, B.; Manceron, L.,
The vibrational spectrum of PdCO isolated in solid argon,
Chem. Phys., 1999, 250, 2, 187, https://doi.org/10.1016/S0301-0104(99)00323-7
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Walker, Hui, et al., 2002
Walker, N.R.; Hui, J.K-H.; Gerry, M.C.L.,
Microwave Spectrum, Geometry, and Hyperfine Constants of PdCO,
J. Phys. Chem. A, 2002, 106, 24, 5803, https://doi.org/10.1021/jp0200831
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.