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Benzene, 1,3,5-trichloro-2,4,6-trifluoro-

Data at NIST subscription sites:

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple335.01KN/AAndon and Martin, 1973Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple334.16KN/APaukov and Glukhikh, 1969Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc684.8KN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Pc32.70barN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.40 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap53.8kJ/molN/ABoublik, Fried, et al., 1984Based on data from 364. - 550. K. See also Basarová and Svoboda, 1991.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
352.70.016Aldrich Chemical Company Inc., 1990BS
352.60.016PCR Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
49.2379.AStephenson and Malanowski, 1987Based on data from 364. - 496. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
19.830335.01Andon and Martin, 1973, 2Anomalous heat capacity between 285 and 305 K. Enthalpy of transition 18.1 J/mol (excess over extrapolated heat capacities).; DH
19.849334.16Paukov and Glukhikh, 1969, 2Smoothed table gives H = 4712 cal/mol, S = 14.12 cal/mol*K.; DH
19.83335.Acree, 1991AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
59.19335.01Andon and Martin, 1973, 2Anomalous; DH
59.40334.16Paukov and Glukhikh, 1969, 2Smoothed; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andon and Martin, 1973
Andon, J.L.; Martin, J.F., Thermodynamic properties of fluorine compounds: xii low-temperature heat capacity and entropy of 1,3,5-trichloro-2,4,6-trifluorobenzene, J. Chem. Soc., Faraday Trans. 1, 1973, 69, 871. [all data]

Paukov and Glukhikh, 1969
Paukov, I.E.; Glukhikh, L.K., The true heat capacity in the range 13-350 c and the absolute entropy and enthalpy of 1,3,5-trichloro-2,4,6-trifluorobenzene, Zh. Fiz. Khim., 1969, 43, 226-8. [all data]

Ambrose, Broderick, et al., 1974
Ambrose, D.; Broderick, B.E.; Townsend, R., The Critical Temperatures and Pressures of Thirty Organic Compounds, J. Appl. Chem. Biotechnol., 1974, 24, 359. [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Basarová and Svoboda, 1991
Basarová, Pavlína; Svoboda, Václav, Calculation of heats of vaporization of halogenated hydrocarbons from saturated vapour pressure data, Fluid Phase Equilibria, 1991, 68, 13-34, https://doi.org/10.1016/0378-3812(91)85008-I . [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Andon and Martin, 1973, 2
Andon, R.J.L.; Martin, J.F., Thermodynamic properties of fluorine compounds. Part 12. Low-temperature heat capacity and entropy of 1,3,5-trichloro-2,4,6-trifluorobenzene, J. Chem. Soc. Faraday Trans., 1973, I 69, 871-875. [all data]

Paukov and Glukhikh, 1969, 2
Paukov, I.E.; Glukhikh, L.K., The true heat capacity in the range 13-350°K and the absolute entropy and enthalpy of 1,3,5-trichloro-2,4,6-trifluorobenzene, Zhur. Fiz. Khim., 1969, 43, 226-228. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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