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Ethane, 1,1,1-trichloro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-177. ± 2.kJ/molReviewManion, 2002weighted average of several measurements; DRB
Deltafliquid-174.kJ/molEqkLevanova, Treger, et al., 1975Flow reactor at 50°C; ALS
Deltafliquid-178.6 ± 0.84kJ/molCcbHu, Sinke, et al., 1972Reanalyzed by Cox and Pilcher, 1970, Original value = -176. ± 0.79 kJ/mol; see Hu and Sinke, 1969; ALS
Deltafliquid-174.8 ± 1.4kJ/molCcrMansson, Ringner, et al., 1971ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1108.0 ± 0.79kJ/molCcbHu, Sinke, et al., 1972see Hu and Sinke, 1969; ALS
Deltacliquid-1112.1 ± 1.3kJ/molCcrMansson, Ringner, et al., 1971ALS
Quantity Value Units Method Reference Comment
liquid226.7J/mol*KN/AAndon, Counsell, et al., 1973DH
liquid227.48J/mol*KN/ARubin, Levedahl, et al., 1944DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
144.4298.15Andon, Counsell, et al., 1973T = 10 to 310 K.; DH
138.9257.29Crowe and Smyth, 1950T = 117 to 260 K. Value is unsmoothed experimental datum.; DH
144.31299.59Rubin, Levedahl, et al., 1944T = 12 to 300 K. Value is unsmoothed experimental datum.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
123.225.Martin and Monti, 1988T = 10 to 225 K. Data given graphically and estimated from graph.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Levanova, Treger, et al., 1975
Levanova, S.V.; Treger, Yu.A.; Velichko, S.M.; Rozhnov, A.M.; Bshneva, L.I.; Talanov, A.I., Equilibrium of the vinylidene chloride-methylchloroform system, Zh. Prikl. Khim. (Leningrad), 1975, 42, 480-481. [all data]

Hu, Sinke, et al., 1972
Hu, A.T.; Sinke, G.C.; Mintz, M.J., The enthalpy of formation of 1,1,1-trichloroethane from enthalpy of combustion and equilibrium studies, J. Chem. Thermodyn., 1972, 4, 239-245. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Hu and Sinke, 1969
Hu, A.T.; Sinke, G.C., Combustion calorimetry of some chlorinated organic compounds, J. Chem. Thermodyn., 1969, 1, 507-513. [all data]

Mansson, Ringner, et al., 1971
Mansson, M.; Ringner, B.; Sunner, S., The enthalpies of combustion and formation of some simple chloroalkanes and chloralkenes 1,1,1-trichloroethane and 1,1-dichloroethene, J. Chem. Thermodyn., 1971, 3, 547-551. [all data]

Andon, Counsell, et al., 1973
Andon, R.J.L.; Counsell, J.F.; Lee, D.A.; Martin, J.F., Thermodynamic properties of aliphatic halogen compounds. Part 2. Heat capacity of 1,1,1-trichloroethane, J. Chem. Soc. Faraday Trans., 1973, I 69, 1721-1726. [all data]

Rubin, Levedahl, et al., 1944
Rubin, T.R.; Levedahl, B.H.; Yost, D.M., The heat capacity, heat of transition, vaporization, vapor pressure and entropy of 1,1,1-trichloroethane, J. Am. Chem. Soc., 1944, 66, 279-282. [all data]

Crowe and Smyth, 1950
Crowe, R.W.; Smyth, C.P., Heat capacities, dielectric constants and molecular rotational freedom in solid trichloroethanes and disubstituted propanes, J. Am. Chem. Soc., 1950, 72, 4009-4015. [all data]

Martin and Monti, 1988
Martin, C.A.; Monti, G.A., Specific heat analysis in 1,1,1-trichloroethane, Thermochim. Acta, 1988, 134, 27-34. [all data]


Notes

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