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Nitric oxide anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.040 ± 0.010N/AVelarde, Habteyes, et al., 2007 
0.0260 ± 0.0050LPESTravers, Cowles, et al., 1989ground state triplet anion
0.024 ± 0.010LPESSiegel, Celotta, et al., 1972 
0.02 ± 0.10CIDTTiernan and Wu, 1978 
0.0250 ± 0.0070ETSBurrow, 1974 
0.10 ± 0.10ECDChen and Wentworth, 1983 
0.02 ± 0.10EndoHughes, Lifschitz, et al., 1973 
0.026 ± 0.022KineParkes and Sugden, 1972 
0.68 ± 0.20EndoRefaey, 1976 
>0.10 ± 0.10NBIENalley, Compton, et al., 1973 
>0.089982EndoBerkowitz, Chupka, et al., 1971 
>0.06 ± 0.10EndoChantry, 1971 
>0.65 ± 0.10EIAEStockdale, Compton, et al., 1969From NO2
0.85 ± 0.10EIAEWilliams and Hamill, 1968From EtONO, nBuONO
0.828255SIPage and Goode, 1969The Magnetron method, lacking mass analysis, is not considered reliable.
0.910647SIFarragher, Page, et al., 1964The Magnetron method, lacking mass analysis, is not considered reliable.

Protonation reactions

Nitric oxide anion + Hydrogen cation = Nitrosyl hydride

By formula: NO- + H+ = HNO

Quantity Value Units Method Reference Comment
Deltar361.27 ± 0.15kcal/molD-EATravers, Cowles, et al., 1989gas phase; ground state triplet anion
Quantity Value Units Method Reference Comment
Deltar354.68 ± 0.34kcal/molH-TSTravers, Cowles, et al., 1989gas phase; ground state triplet anion

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Velarde, Habteyes, et al., 2007
Velarde, L.; Habteyes, T.; Grumbling, E.R.; Pichugin, K.; Sanov, A., Solvent resonance effect on the anisotropy of NO-(N2O)(n) cluster anion photodetachment, J. Chem. Phys., 2007, 127, 8, 084302, https://doi.org/10.1063/1.2766948 . [all data]

Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B., Reinvestigation of the Electron Affinities of O2 and NO, Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6 . [all data]

Siegel, Celotta, et al., 1972
Siegel, M.W.; Celotta, R.J.; Hall, J.L.; Levine, J.; Bennett, R.A., Molecular Photodetachment Spectroscopy. I. The Electron Affinity of Nitric Oxide and the Molecular Constants of NO-, Phys. Rev. A, 1972, 6, 2, 607, https://doi.org/10.1103/PhysRevA.6.607 . [all data]

Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C., Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds, Adv. Mass Spectrom., 1978, 7A, 136. [all data]

Burrow, 1974
Burrow, P.D., Temporary negative ion formation in NO and O2, Chem. Phys. Lett., 1974, 26, 265. [all data]

Chen and Wentworth, 1983
Chen, E.C.M.; Wentworth, W.E., Determination of molecular electron affinities using the electron capture detector in the pulse sampling mode at steady state, J. Phys. Chem., 1983, 87, 45. [all data]

Hughes, Lifschitz, et al., 1973
Hughes, B.M.; Lifschitz, C.; Tiernan, T.O., Electron affinities from endothermic negative-ion charge-transfer reactions. III. NO, NO2, S2, CS2, Cl2, Br2, I2, and C2H, J. Chem. Phys., 1973, 59, 3162. [all data]

Parkes and Sugden, 1972
Parkes, D.A.; Sugden, T.M., Electron attachment and detachment in nitric oxide, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 600. [all data]

Refaey, 1976
Refaey, K.M.A., Endoergic ion-molecule-Collision Processes of Negative Ions. IV. Collisions of I- on NO2, N2O and NO, Int. J. Mass Spectrom. Ion Phys., 1976, 21, 21. [all data]

Nalley, Compton, et al., 1973
Nalley, S.J.; Compton, R.N.; Schweinler, H.C.; Anderson, V.E., Molecular electron affinities from collisional ionization of cesium. I. NO, NO2, and N2O, J. Chem. Phys., 1973, 59, 4125. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Gutman, D., Electron Affinities of O2, O3, NO, NO2, and NO3 by Endothermic Charge Transfer, J. Chem. Phys., 1971, 55, 6, 2733, https://doi.org/10.1063/1.1676488 . [all data]

Chantry, 1971
Chantry, P.J., Doppler broadening in beam experiments, J. Chem. Phys., 1971, 55, 2746. [all data]

Stockdale, Compton, et al., 1969
Stockdale, J.A.D.; Compton, R.N.; Hurst, G.S.; Reinhardt, P.W., Collisions of Monoenergetic Electrons with NO2: Possible Lower Limits to the Electron Affinities of O2 and NO, J. Chem. Phys., 1969, 50, 5, 2176, https://doi.org/10.1063/1.1671347 . [all data]

Williams and Hamill, 1968
Williams, J.M.; Hamill, W.H., Ionization potentials of molecules and free radicals and appearance potentials by electron impact in the mass spectrometer, J. Chem. Phys., 1968, 49, 4467. [all data]

Page and Goode, 1969
Page, F.M.; Goode, G.C., Negative Ions and the Magnetron., Wiley, NY, 1969. [all data]

Farragher, Page, et al., 1964
Farragher, A.L.; Page, F.M.; Wheeler, R.C., Electron Affinities of the Nitrogen Oxides, Disc. Faraday Soc., 1964, 37, 203, https://doi.org/10.1039/df9643700203 . [all data]


Notes

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