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Disilane,pentamethylphenyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.39CTSakurai, Ichinose, et al., 1984LBLHLM
8.35 ± 0.15EIGaidis, Briggs, et al., 1971LLK
7.82EIBock and Alt, 1970RDSH
8.35PEPitt and Bock, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9Si+10.08 ± 0.09C6H5Si(CH3EIGaidis, Briggs, et al., 1971LLK
C8H11Si+9.86 ± 0.06Si(CH3)3EIGaidis, Briggs, et al., 1971LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sakurai, Ichinose, et al., 1984
Sakurai, H.; Ichinose, M.; Kira, M.; Traylor, T.G., Ultraviolet, charge-transfer, and photoelectron spectra of phenyl-substituted Group 4B catenates, PhMe2E-E'Me3 (E = Si, Ge; E' = C, Si, Ge, Sn), Chem. Lett., 1984, 1383. [all data]

Gaidis, Briggs, et al., 1971
Gaidis, J.M.; Briggs, P.R.; Shannon, T.W., Mass spectra of disilanes. Phenyl-silicon interaction and silicon-silicon bond strength, J. Phys. Chem., 1971, 75, 974. [all data]

Bock and Alt, 1970
Bock, H.; Alt, H., d-Orbital effects in silicon substituted «pi»-electron systems. XXIV. Charge-transfer studies of silyl- and alkylbenzenes, J. Am. Chem. Soc., 1970, 92, 1569. [all data]

Pitt and Bock, 1972
Pitt, C.G.; Bock, H., «sigma»-«pi» Mixing in phenylpentamethyldisilane, J. Chem. Soc., Chem. Commun., 1972, 28. [all data]


Notes

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