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Indium monofluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
9.6 ± 0.5EIMurad, Hildenbrand, et al., 1966

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through January, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 115In19F
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
            45709.1 HQ
Barrow, Jacquest, et al., 1954
D [47803] 1          D larrow X R 47536 H
Barrow, Jacquest, et al., 1954
C 1Pi 42809.2 463.9 HQ 7.35 2  0.2674 0.00472  0.036E-5  1.966 C lrarrow X RV 42772.3 Z
Welti and Barrow, 1951; Barrow, Glaser, et al., 1955; missing citation
B 3Pi1 31255.74 572.25 HQ 2.63 3  0.27362 4 0.00204  (0.025E-5)  1.9440 B lrarrow X V 31274.18 Z
Welti and Barrow, 1951; Barrow, Jacquest, et al., 1954; Barrow, Glaser, et al., 1955
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
A 3Pi0+ 30445.86 (575.2) Z 3.676  0.27320 4 0.00202  (0.025E-5)  1.9455 A lrarrow X V 30465.52 Z
Welti and Barrow, 1951; Barrow, Jacquest, et al., 1954; Barrow, Glaser, et al., 1955
X 1Sigma+ 0 535.35 Z 2.64  0.26232411 0.00187977 5  0.0252E-5  1.985396 6  
Lovas and Torring, 1969; Hoeft, Lovas, et al., 1970
Mol. beam el. reson. 7
Hammerle, van Ausdal, et al., 1972

Notes

1Weak ssytem.
2This state may have a potential maximum of ~0.21 eV Barrow, 1960, Murad, Hildenbrand, et al., 1966.
3missing note
4From the B' - B" values of Barrow, Glaser, et al., 1955, combined with B" from the microwave spectrum.
5missing note
6Microwave sp. 9
7Hyperfine interaction constants.
8Thermochemical value (mass-spectrom.) Murad, Hildenbrand, et al., 1966. Flame photometry gives 5.4 eV Bulewicz, Phillips, et al., 1961.
9muel(v=0) = 3.40 D Hoeft, Lovas, et al., 1970.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murad, Hildenbrand, et al., 1966
Murad, E.; Hildenbrand, D.L.; Main, R.P., Dissociation energies of group IIIA monofluorides-the possibility of potential maxima in their excited H states,, J. Chem. Phys., 1966, 45, 263. [all data]

Barrow, Jacquest, et al., 1954
Barrow, R.F.; Jacquest, J.A.T.; Thompson, E.W., The ultra-violet emission spectra of the gaseous monofluorides of gallium and indium, Proc. Phys. Soc. London Sect. A, 1954, 67, 528. [all data]

Welti and Barrow, 1951
Welti, D.; Barrow, R.F., Ultra-violet absorption spectra of gallium and indium monofluorides, Nature (London), 1951, 168, 161. [all data]

Barrow, Glaser, et al., 1955
Barrow, R.F.; Glaser, D.V.; Zeeman, P.B., Rotational analysis of bands of the A3«PI»0+, B3«PI»1-X1«SIGMA»+ systems of indium monofluoride, Proc. Phys. Soc. London Sect. A, 1955, 68, 962. [all data]

Lovas and Torring, 1969
Lovas, F.J.; Torring, T., Microwave rotational spectrum of indium monofluoride, Z. Naturforsch. A, 1969, 24, 634. [all data]

Hoeft, Lovas, et al., 1970
Hoeft, J.; Lovas, F.J.; Tiemann, E.; Torring, T., Microwave absorption spectra of AlF, GaF, InF, and TlF, Z. Naturforsch. A, 1970, 25, 1029. [all data]

Hammerle, van Ausdal, et al., 1972
Hammerle, R.H.; van Ausdal, R.; Zorn, J.C., Hyperfine structure of indium fluoride, J. Chem. Phys., 1972, 57, 4068. [all data]

Barrow, 1960
Barrow, R.F., Dissociation energies of the gaseous monohalides of boron, aluminium, gallium, indium, and thallium, Trans. Faraday Soc., 1960, 56, 952. [all data]

Bulewicz, Phillips, et al., 1961
Bulewicz, E.M.; Phillips, L.F.; Sugden, T.M., Determination of dissociation constants and heats of formation of simple molecules by flame photometry. Part 8. Stabilities of the gaseous diatomic halides of certain metals, Trans. Faraday Soc., 1961, 57, 921. [all data]


Notes

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