Propylamine
- Formula: C3H9N
- Molecular weight: 59.1103
- IUPAC Standard InChI: InChI=1S/C3H9N/c1-2-3-4/h2-4H2,1H3
- IUPAC Standard InChIKey: WGYKZJWCGVVSQN-UHFFFAOYSA-N
- CAS Registry Number: 107-10-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1-Propanamine; n-Propylamine; Mono-n-propylamine; Monopropylamine; Propanamine; 1-Aminopropane; 1-Propylamine; n-C3H7NH2; Rcra waste number U194; UN 1277; NSC 7490
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -101.5 ± 0.4 | kJ/mol | Ccr | Smith and Good, 1967 | ALS |
| ΔfH°liquid | -138. | kJ/mol | Ccb | Lemoult, 1907 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -2365. ± 3. | kJ/mol | Ccr | Smith and Good, 1967 | ALS |
| ΔcH°liquid | -2344. | kJ/mol | Ccb | Lemoult, 1907 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid | 227.44 | J/mol*K | N/A | Finke, Messerly, et al., 1972 | DH |
| S°liquid | 228.2 | J/mol*K | N/A | Vasil'ev, Petrov, et al., 1971 | Extrapolation below 60 K, 26.7 J/mol*K.; DH |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 162.51 | 298.15 | Finke, Messerly, et al., 1972 | T = 12 to 350 K.; DH |
| 160. | 298.15 | Konicek and Wadso, 1971 | DH |
| 166.4 | 298.15 | Vasil'ev, Petrov, et al., 1971 | T = 60 to 300 K. Details deposited VINITI, No. 2530-71, 30 Jan 1971.; DH |
| 162.3 | 298.15 | Smith and Good, 1967 | DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Smith and Good, 1967
Smith, N.K.; Good, W.D.,
Enthalpies of combustion and formation of propylamine, isopropylamine, and tert-butylamine,
J. Chem. Eng. Data, 1967, 12, 572-574. [all data]
Lemoult, 1907
Lemoult, M.P.,
Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques,
Ann. Chim. Phys., 1907, 12, 395-432. [all data]
Finke, Messerly, et al., 1972
Finke, H.L.; Messerly, J.F.; Todd, S.S.,
Thermodynamic properties of acrylonitrile, 1-aminopropane, 2-aminopropane, and 2-methyl-2-aminopropane,
J. Chem. Thermodynam., 1972, 4, 359-374. [all data]
Vasil'ev, Petrov, et al., 1971
Vasil'ev, I.A.; Petrov, V.M.; Ignat'ev, V.M.; Vvedenskii, A.A.,
Thermodynamic functions of a series of aliphatic amines. III. Entropy of n-propylamine,
Zhur. Fiz. Khim., 1971, 45, 1316. [all data]
Konicek and Wadso, 1971
Konicek, J.; Wadso, I.,
Thermochemical properties of some carboxylic acids, amines and N-substituted amides in aqueous solution,
Acta Chem. Scand., 1971, 25, 1541-1551. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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