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Benzene, nitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid2.98 ± 0.13kcal/molCcbLebedeva, Katin, et al., 1971Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 2.32 ± 0.10 kcal/mol; ALS
Deltafliquid-3.9kcal/molCcbSwarts, 1914See 14SWA2; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-738.07 ± 0.10kcal/molCcbLebedeva, Katin, et al., 1971ALS
Deltacliquid-739.9kcal/molCcbGarner and Abernethy, 1921ALS
Deltacliquid-734.65kcal/molCcbSwarts, 1914See 14SWA2; ALS
Quantity Value Units Method Reference Comment
liquid53.61cal/mol*KN/AParks, Todd, et al., 1936Extrapolation below 90 K, 62.13 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
42.38303.15Reddy, 1986T = 303.15, 313.15 K.; DH
43.291298.15Lainez, Rodrigo, et al., 1985DH
42.1303.Pacor, 1967DH
43.07293.Rastorguev and Ganiev, 1967T = 293 to 373 K.; DH
45.10335.5Lutskii and Panova, 1958T = 62 to 141°C. Value is unsmoothed experimental datum.; DH
43.009293.15Mazur, 1939T = 5 to 20°C.; DH
43.00293.Mazur, 1939, 2T = 5 to 20°C.; DH
44.620298.1Parks, Todd, et al., 1936T = 90 to 300 K.; DH
44.630298.Parks and Todd, 1934T = 273 to 299 K.; DH
42.40303.Willams and Daniels, 1924T = 303 to 358 K. Equation only.; DH
42.50298.von Reis, 1881T = 291 to 486 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedeva, Katin, et al., 1971
Lebedeva, N.D.; Katin, Y.A.; Akhmedova, G.Y., Standard enthalpy of formation of nitrobenzene, Russ. J. Phys. Chem. (Engl. Transl.), 1971, 45, 1192-1193. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Swarts, 1914
Swarts, F., Sur la chaleur de combustion de quelques derives nitres aromatlques, Recl. Trav. Chim. Pays-Bas, 1914, 33, 281-298. [all data]

Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L., Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series, Proc. Roy. Soc. London A, 1921, 213-235. [all data]

Parks, Todd, et al., 1936
Parks, G.S.; Todd, S.S.; Moore, W.A., Thermal data on organic compounds. XVI. Some heat capacity, entropy and free energy data for typical benzene derivatives and heterocyclic compounds, J. Am. Chem. Soc., 1936, 58, 398-401. [all data]

Reddy, 1986
Reddy, K.S., Isentropic compressibilities of binary liquid mixtures at 303.15 and 313.15 K, J. Chem. Eng. Data, 1986, 31, 238-240. [all data]

Lainez, Rodrigo, et al., 1985
Lainez, A.; Rodrigo, M.; Roux, A.H.; Grolier, J.-P.E.; Wilhelm, E., Relations between structure and thermodynamic properties. Heat capacities of polar substances (nitrobenzene and benzonitrile) in alkane solutions, Calorim. Anal. Therm., 1985, 16, 153-158. [all data]

Pacor, 1967
Pacor, P., Applicability of the DuPont 900 DTA apparatus in quantitative differential thermal analysis, Anal. Chim. Acta, 1967, 37, 200-208. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]

Lutskii and Panova, 1958
Lutskii, A.E.; Panova, A.N., Specific heat of liquid nitrobenzene, Zhur. Fiz. Khim., 1958, 32, 2183-2185. [all data]

Mazur, 1939
Mazur, J., Über die spezifische Wärme des Nitrobenzols, Acta Phys. Pol., 1939, 7, 290-304. [all data]

Mazur, 1939, 2
Mazur, J., Über die spezifische Wärme des Äthyläthers, des Nitrobenzols und des Schwefelkohlenstoffs, Z. Physik., 1939, 113, 710-720. [all data]

Parks and Todd, 1934
Parks, G.S.; Todd, S.S., Some heat capacity data for liquid nitrobenzene, no indication of allotropy, J. Chem. Phys., 1934, 2, 440-441. [all data]

Willams and Daniels, 1924
Willams, J.W.; Daniels, F., The specific heats of certain organic liquids at elevated temperatures, J. Am. Chem. Soc., 1924, 46, 903-917. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

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