Perfluoroperoxide

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 17000 U gas Broderson, Frisch, et al., 1937

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a 1 OO stretch 1210 ± 3 gas IR Kim and Campbell, 1985
2 OF s-stretch 630 ± 3 gas IR Kim and Campbell, 1985
2 OF s-stretch 627 Ar IR Arkell, 1965
Gardiner, Lawrence, et al., 1971
Jacox, 1980
2 OF s-stretch 624 O2 IR Spratley, Turner, et al., 1966
3 Deform. 360 T gas IR Kim and Campbell, 1985
3 Deform. 366 Ar IR Gardiner, Lawrence, et al., 1971
3 Deform. 368 O2 IR Spratley, Turner, et al., 1966
4 Torsion 202 T gas IR Kim and Campbell, 1985
b 5 OF a-stretch 614 ± 3 gas IR Kim and Campbell, 1985
5 OF a-stretch 612 Ar IR Arkell, 1965
Gardiner, Lawrence, et al., 1971
Jacox, 1980
5 OF a-stretch 612 O2 IR Spratley, Turner, et al., 1966
6 Deform. 466 Ar IR Gardiner, Lawrence, et al., 1971
Jacox, 1980
6 Deform. 462 O2 IR Spratley, Turner, et al., 1966

Additional references: Jacox, 1994, page 225; Jackson, 1962

Notes

UUpper bound
TTentative assignment or approximate value
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Broderson, Frisch, et al., 1937
Broderson, P.H.; Frisch, P.; Schumacher, H.-J., Z. Phys. Chem. B37, 1937, 25. [all data]

Kim and Campbell, 1985
Kim, K.C.; Campbell, G.M., The infrared spectrum and vibrational intensity of gaseous dioxygen difluoride (foof), J. Mol. Struct., 1985, 129, 3-4, 263, https://doi.org/10.1016/0022-2860(85)80170-8 . [all data]

Arkell, 1965
Arkell, A., None, J. Am. Chem. Soc., 1965, 87, 18, 4057, https://doi.org/10.1021/ja01096a006 . [all data]

Gardiner, Lawrence, et al., 1971
Gardiner, D.J.; Lawrence, N.J.; Turner, J.J., J. Chem. Soc. A, 1971, 400. [all data]

Jacox, 1980
Jacox, M.E., The reaction of F atoms with O2 in an argon matrix, J. Mol. Spectrosc., 1980, 84, 1, 74, https://doi.org/10.1016/0022-2852(80)90240-4 . [all data]

Spratley, Turner, et al., 1966
Spratley, R.D.; Turner, J.J.; Pimentel, G.C., Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding, J. Chem. Phys., 1966, 44, 5, 2063, https://doi.org/10.1063/1.1726981 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jackson, 1962
Jackson, R.H., J. Chem. Soc., 1962, 4585. [all data]


Notes

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