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Phosphoryl fluoride


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C3nu     Symmetry Number sigma = 3


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1 1 PO str 1417  B 1415 M gas 1416.8 p gas
a1 2 PF3 s-str 873  B 873 M gas 872.7 p gas
a1 3 PF3 s-deform 472  B 473 S gas 472.4 gas OV(«nu»5 )in Raman
e 4 PF3 d-str 991  C 990 VS gas 991.0 dp gas
e 5 PF3 d-deform 482  C 485 M gas 482.0 dp gas
e 6 PO bend 336  C 335.5 dp gas

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
pPolarized
dpDepolarized
OVOverlapped by band indicated in parentheses.
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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