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Phosphoryl fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
IE (evaluated)12.76 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)165.9kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity158.7kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
13.34EINeskovic, Miletic, et al., 1983LBLHLM
12.77 ± 0.04PEBasset and Lloyd, 1972LLK
12.75PEFrost, Herring, et al., 1971LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FOP+13.53F2-EINeskovic, Miletic, et al., 1983LBLHLM
F2OP+13.34FEINeskovic, Miletic, et al., 1983LBLHLM
F2OP+11.69F-EINeskovic, Miletic, et al., 1983LBLHLM
OP+16.83F-+F2EINeskovic, Miletic, et al., 1983LBLHLM

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Neskovic, Miletic, et al., 1983
Neskovic, O.; Miletic, M.; Veljkovic, M.; Golobocantin, D.; Zmbov, K.F., Ionization and fragmentation of phosphorous oxyfluoride by electron impact, Int. J. Mass Spectrom. Ion Processes, 1983, 47, 141. [all data]

Basset and Lloyd, 1972
Basset, P.J.; Lloyd, D.R., Photoelectron spectra of halides. Part III. Trifluorides and oxide trifluorides of nitrogen and phosphorus, and phosphorus oxide trichloride, J. Chem. Soc. Dalton Trans., 1972, 248. [all data]

Frost, Herring, et al., 1971
Frost, D.C.; Herring, F.G.; Mitchell, K.A.R.; Stenhouse, I.A., Photoelectron spectra and electronic structures of trifluoramine oxide and trifluorophosphine oxide, J. Am. Chem. Soc., 1971, 93, 1596. [all data]


Notes

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