Hexaphenylditin

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas855. ± 11.kJ/molReviewMartinho SimõesSelected data
Δfgas955. ± 18.kJ/molReviewMartinho Simões 
Δfgas863. ± 30.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid666.6 ± 9.6kJ/molReviewMartinho SimõesSelected data
Δfsolid767. ± 17.kJ/molReviewMartinho Simões 
Δfsolid675. ± 30.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcsolid-20275.7 ± 8.4kJ/molCC-RBCarson, Laye, et al., 1970Please also see Pedley and Rylance, 1977.
Δcsolid-20376. ± 17.kJ/molCC-RBTel'noi and Rabinovich, 1966Please also see Cox and Pilcher, 1970.
Δcsolid-20284. ± 29.kJ/molCC-RBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub188.3 ± 4.2kJ/molCC-RBKeiser and Kana'an, 1969MS
Δsub188.3 ± 4.2kJ/molME,TEKeiser and Kana'an, 1969, 2AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C18H15Sn+8.7 ± 0.2?EIChambers and Glockling, 1970 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 156966

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Carson, Laye, et al., 1970
Carson, a.S.; Laye, P.G.; Spencer, J.A.; Steele, W.V., The enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed aneroid calorimeter. The enthalpy of formation of di-tin hexaphenyl and some associated bond energies, J. Chem. Thermodyn., 1970, 2, 659. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1966
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1966, 40, 842. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Keiser and Kana'an, 1969
Keiser, D.; Kana'an, A.S., J. Phys. Chem., 1969, 73, 4264. [all data]

Keiser and Kana'an, 1969, 2
Keiser, D.; Kana'an, A.S., Enthalpy and entropy of sublimation of tetraphenyltin and hexaphenylditin. Bond dissociation energy of Sn-C and Sn-Sn, J. Phys. Chem., 1969, 73, 12, 4264-4269, https://doi.org/10.1021/j100846a038 . [all data]

Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F., Electron impact determination of heats of formation and bond energies in triphenyltin compounds, Inorg. Chim. Acta, 1970, 4, 150. [all data]


Notes

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