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Cesium dimer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Cs2+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.469 ± 0.015LPESMcHugh, Eaton, et al., 1989Vertical Detachment Energy: 0.511±0.010 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
3.7 ± 0.1PIKappes, Radi, et al., 1985LBLHLM
<=3.76 ± 0.06SHelm and Moller, 1983LBLHLM
3.68EVALMarr and Wherrett, 1972LLK
3.60PIMarr and Wherrett, 1972LLK
3.8 ± 0.1PIFoster, Leckenby, et al., 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McHugh, Eaton, et al., 1989
McHugh, K.M.; Eaton, J.G.; Lee, G.H.; Sarkas, H.W.; Kidder, L.H.; Snodgrass, J.T.; Manaa, M.R.; Bowen, K.H., Photoelectron Spectra of the alkali metal cluster Anions: Na-,n=2-5, K-,n=2-7, Rb-,n=2-3, and Cs-,n=2-3, J. Chem. Phys., 1989, 91, 6, 3792, https://doi.org/10.1063/1.456861 . [all data]

Kappes, Radi, et al., 1985
Kappes, M.M.; Radi, P.; Schar, M.; Schumacher, E., Photoionization measurements on dialkali monohalides generated in supersonic nozzle beams, Chem. Phys. Lett., 1985, 113, 243. [all data]

Helm and Moller, 1983
Helm, H.; Moller, R., Bound-free spectroscopy of Cs2+, Phys. Rev. A:, 1983, 27, 2493. [all data]

Marr and Wherrett, 1972
Marr, G.V.; Wherrett, S.R., The ionization of caesium vapour by the method of space charge amplification, J. Phys. B:, 1972, 5, 1735. [all data]

Foster, Leckenby, et al., 1969
Foster, P.J.; Leckenby, R.E.; Robbins, E.J., The ionization potentials of clustered alkali metal atoms, J. Phys. B:, 1969, 2, 478. [all data]


Notes

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