η4-Trimethylenemethane-iron tricarbonyl-
- Formula: C7H6FeO3
- Molecular weight: 193.966
- CAS Registry Number: 12078-33-0
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.910647 | IMRE | Sharpe and Kebarle, 1993 | ΔGea(343 K)= -17.0 kcal/mol; ΔSea estimated as -10 eu; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.32 ± 0.02 | PE | Dewar and Worley, 1969 | RDSH |
| 8.63 | PE | Worley, Webb, et al., 1980 | Vertical value; LLK |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sharpe and Kebarle, 1993
Sharpe, P.; Kebarle, P.,
Electron Affinities, Enthalpy, and Entropy of Electron Attachment of Several eta-4-(Olefin)Fe(CO)3 Complexes and Electron-Transfer Kinetics,
J. Am. Chem. Soc., 1993, 115, 2, 782, https://doi.org/10.1021/ja00055a059
. [all data]
Dewar and Worley, 1969
Dewar, M.J.S.; Worley, S.D.,
Photoelectron spectrum of trimethylenemethane iron tricarbonyl and a theoretical study of trimethylenemethane,
J. Chem. Phys., 1969, 51, 1672. [all data]
Worley, Webb, et al., 1980
Worley, S.D.; Webb, T.R.; Gibson, D.H.; Ong, T.-S.,
The photoelectron spectra of some iron tricarbonyl complexes of 4π-electron donor ligands,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 189. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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