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Stannane, tetraphenyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus501.KN/AAdams and Carson, 1969Uncertainty assigned by TRC = 2. K; TRC
Tfus503.2KN/ASangster and Irvine, 1956Uncertainty assigned by TRC = 4. K; TRC
Tfus499.1KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.7 K; TRC
Tfus499.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltasub161.1 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Adams, Carson, et al., 1969.; AC
Deltasub59.5kJ/molN/ANewkirk, 1972See also Marcus and Loewenschuss, 1986.; AC
Deltasub161.1 ± 4.2kJ/molCC-SBKeiser and Kana'an, 1969MS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
151.7427.AStephenson and Malanowski, 1987Based on data from 393. - 461. K.; AC
152.5 ± 0.6428. - 454.TEKeiser and Kana'an, 1969, 2AC
151.8 ± 1.1393. - 461.MEKeiser and Kana'an, 1969, 2AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
37.2502.2DSCVitoria and Walkley, 1969AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adams and Carson, 1969
Adams, G.P.; Carson, A.S., The Enthalpy of COmbustion of Organimetallic Compounds Measured with a Vacuum-jacketed Aneroud Calorimeter. The Enthalpy of Formation of Tin Tetraphenyl, J. Chem. Thermodyn., 1969, 1, 393-6. [all data]

Sangster and Irvine, 1956
Sangster, R.C.; Irvine, J.W., Study of Organic Scintillators, J. Chem. Phys., 1956, 24, 670. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G., The enthalpy of combustion of organometallic compounds measured with a vacuum-jacketed aneroid calorimeter The enthalpy of formation of tin tetraphenyl, The Journal of Chemical Thermodynamics, 1969, 1, 4, 393-396, https://doi.org/10.1016/0021-9614(69)90069-X . [all data]

Newkirk, 1972
Newkirk, Herbert W., Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead, Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9 . [all data]

Marcus and Loewenschuss, 1986
Marcus, Yizhak; Loewenschuss, Aharon, Entropies of tetrahedral M---phenyl species, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 3, 993, https://doi.org/10.1039/f19868200993 . [all data]

Keiser and Kana'an, 1969
Keiser, D.; Kana'an, A.S., J. Phys. Chem., 1969, 73, 4264. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Keiser and Kana'an, 1969, 2
Keiser, D.; Kana'an, A.S., Enthalpy and entropy of sublimation of tetraphenyltin and hexaphenylditin. Bond dissociation energy of Sn-C and Sn-Sn, J. Phys. Chem., 1969, 73, 12, 4264-4269, https://doi.org/10.1021/j100846a038 . [all data]

Vitoria and Walkley, 1969
Vitoria, M.; Walkley, John, Studies in regular solution theory. Part 1.?Solubolity studies of tetraphenyltin in simple non-polar solvents, Trans. Faraday Soc., 1969, 65, 57, https://doi.org/10.1039/tf9696500057 . [all data]


Notes

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