Stannane, tetrabutyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-218.6 ± 7.4kJ/molReviewMartinho Simões 
Δfgas-216.1 ± 4.2kJ/molReviewMartinho Simões 
Δfgas-217.4 ± 4.5kJ/molReviewMartinho SimõesSelected data. Average of the values from Davies, Pope, et al., 1963 and Lautsch, Tröber, et al., 1963.
Δfgas-154. ± 17.kJ/molReviewMartinho Simões 
Δfgas-333.7kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-301.4 ± 7.1kJ/molReviewMartinho Simões 
Δfliquid-298.9 ± 3.6kJ/molReviewMartinho Simões 
Δfliquid-300.2 ± 4.0kJ/molReviewMartinho SimõesSelected data. Average of the values from Davies, Pope, et al., 1963 and Lautsch, Tröber, et al., 1963.
Δfliquid-237. ± 17.kJ/molReviewMartinho Simões 
Δfliquid-416.5kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcliquid-11717.3 ± 6.7kJ/molCC-SBDavies, Pope, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.
Δcliquid-11719.8 ± 2.9kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.
Δcliquid-11782. ± 17.kJ/molCC-SBDillard, McNeill, et al., 1958 
Δcliquid-11602.2kJ/molCC-SBJones, Evans, et al., 1935 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap82.8 ± 2.1kJ/molCC-SBDavies, Pope, et al., 1963MS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
67.8 ± 0.5425.Baev, 2001Based on data from 389. - 462. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
373.8 - 573.84.957522882.0446.532Umilin and Tsinovoi, 1968Coefficents calculated by NIST from author's data.

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 290891

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Dillard, McNeill, et al., 1958
Dillard, C.R.; McNeill, E.H.; Simmons, D.E.; Yeldell, J.B., J. Am. Chem. Soc., 1958, 80, 3607. [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Umilin and Tsinovoi, 1968
Umilin, V.A.; Tsinovoi, Y.N., Vapor Pressure of Tetrabutyltin, Zh. Fiz. Khim., 1968, 42, 2320-2322. [all data]


Notes

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