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Formic-d acid


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
11.57EIBernecker and Long, 1961

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CDO+13.19 ± 0.03OHEIPritchard and Harrison, 1968 
CDO2+12.4 ± 0.1HEIPritchard, Thynne, et al., 1968 
CHO2+12.8 ± 0.1DEIPritchard, Thynne, et al., 1968 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bernecker and Long, 1961
Bernecker, R.R.; Long, F., Some organic positive ions and their parent radicals and molecules, J. Phys. Chem., 1961, 65, 1565. [all data]

Pritchard and Harrison, 1968
Pritchard, H.; Harrison, A.G., Heat of formation of CHO+, J. Chem. Phys., 1968, 48, 2827. [all data]

Pritchard, Thynne, et al., 1968
Pritchard, H.; Thynne, J.C.J.; Harrison, A.G., Ionmolecule reactions in formic-d acid and methyl formate, Can. J. Chem., 1968, 46, 2141. [all data]


Notes

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