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Difluoroborane


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 BH stretch 2620.8 ± 0.5 gas IR Coyle, Ritter, et al., 1964
Perec and Becka, 1965
Lynds and Bass, 1965
Porter and Wason, 1965
1 BH stretch 2644 N2 IR Shirk and Shirk, 1983
2 BF2 s-stretch 1164.2 ± 0.5 gas IR Coyle, Ritter, et al., 1964
Perec and Becka, 1965
Lynds and Bass, 1965
Porter and Wason, 1965
2 BF2 s-stretch 1156 N2 IR Shirk and Shirk, 1983
3 BF2 scissors 541.5 ± 0.5 gas IR Coyle, Ritter, et al., 1964
Perec and Becka, 1965
Lynds and Bass, 1965
Porter and Wason, 1965
3 BF2 scissors 542 N2 IR Shirk and Shirk, 1983
b1 4 OPLA 923.5 ± 0.5 gas IR Coyle, Ritter, et al., 1964
Perec and Becka, 1965
Lynds and Bass, 1965
Porter and Wason, 1965
4 OPLA 918 N2 IR Shirk and Shirk, 1983
b2 5 BF2 a-stretch 1402 vs gas IR Coyle, Ritter, et al., 1964
Perec and Becka, 1965
Porter and Wason, 1965
5 BF2 a-stretch 1385.1 N2 IR Shirk and Shirk, 1983

Additional references: Jacox, 1998, page 238; Kasuya, Lafferty, et al., 1968; Westwood, Lewis-Bevan, et al., 1984

Notes

vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Coyle, Ritter, et al., 1964
Coyle, T.D.; Ritter, J.J.; Farrar, T.C., Proc. Chem. Soc., 1964, 25. [all data]

Perec and Becka, 1965
Perec, M.; Becka, L.N., Infrared Spectra of Difluoroborane and Difluoroborane-d, J. Chem. Phys., 1965, 43, 2, 721, https://doi.org/10.1063/1.1696796 . [all data]

Lynds and Bass, 1965
Lynds, L.; Bass, C.D., Vibrational---Rotational Spectrum of Difluoroborane and Difluoroborane-d, J. Chem. Phys., 1965, 43, 12, 4357, https://doi.org/10.1063/1.1696697 . [all data]

Porter and Wason, 1965
Porter, R.F.; Wason, S.K., Reaction of Boroxine with BF3(g). Infrared Spectrum and Stability of HBF2(g), J. Phys. Chem., 1965, 69, 7, 2208, https://doi.org/10.1021/j100891a010 . [all data]

Shirk and Shirk, 1983
Shirk, A.E.; Shirk, J.S., Matrix isolation-mass spectroscopy study of the reaction of boron trifluoride with trimethylamine-alane and trimethylamine-gallane, Inorg. Chem., 1983, 22, 1, 72, https://doi.org/10.1021/ic00143a018 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Kasuya, Lafferty, et al., 1968
Kasuya, T.; Lafferty, W.J.; Lide, D.R., Microwave Spectrum, Structure, Boron Quadrupole Coupling Constants, and Dipole Moment of Difluoroborane, J. Chem. Phys., 1968, 48, 1, 1, https://doi.org/10.1063/1.1664452 . [all data]

Westwood, Lewis-Bevan, et al., 1984
Westwood, N.P.C.; Lewis-Bevan, W.; Gerry, M.C.L., The microwave spectrum and centrifugal distortion constants of difluoroborane, HBF2, J. Mol. Spectrosc., 1984, 106, 1, 227, https://doi.org/10.1016/0022-2852(84)90095-X . [all data]


Notes

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