Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Trichlorosilyl


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 43700 T gas Irikura, Johnson, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 Umbrella 282 ± 30 gas MPI Irikura, Johnson, et al., 1992

State:   G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 43700 T gas Irikura, Johnson, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 Umbrella 261 ± 15 gas MPI Irikura, Johnson, et al., 1992

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 43700 T gas Irikura, Johnson, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 Umbrella 262 ± 16 gas MPI Irikura, Johnson, et al., 1992

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SiCl stretch 470 m Ar IR Jacox and Milligan, 1968
Miller and Andrews, 1981
e 3 SiCl stretch 582 vs Ar IR Jacox and Milligan, 1968
Miller and Andrews, 1981

Additional references: Jacox, 1994, page 218; Leray and Roncin, 1965

Notes

mMedium
vsVery strong
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Irikura, Johnson, et al., 1992
Irikura, K.K.; Johnson, R.D., III; Hudgens, J.W., Electronic spectrum of the trichlorosilyl radical, J. Phys. Chem., 1992, 96, 11, 4306, https://doi.org/10.1021/j100190a038 . [all data]

Jacox and Milligan, 1968
Jacox, M.E.; Milligan, D.E., Matrix-Isolation Study of the Vacuum-Ultraviolet Photolysis of Trichlorosilane. The Infrared Spectrum of the Free Radical SiCl3, J. Chem. Phys., 1968, 49, 7, 3130, https://doi.org/10.1063/1.1670560 . [all data]

Miller and Andrews, 1981
Miller, J.H.; Andrews, L., Matrix spectroscopy of the argon resonance photolysis products of group IV chlorides, J. Mol. Struct., 1981, 77, 1-2, 65, https://doi.org/10.1016/0022-2860(81)85267-2 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Leray and Roncin, 1965
Leray, N.; Roncin, J., Hyperfine Interaction of the Chlorine Nucleus in a Solid Matrix, J. Chem. Phys., 1965, 42, 2, 800, https://doi.org/10.1063/1.1696018 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References