Benzenamine, N-(phenylmethylene)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tfus324.15KN/AMeic and Baranovic, 1989Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δsub98.1 ± 1.2kJ/molTVerevkin, Morgenthaler, et al., 1997AC
Δsub93.7 ± 0.9kJ/molCKirchner, Acree, et al., 1986ALS
Δsub93.7kJ/molN/AKirchner, Acree, et al., 1986DRB
Δsub93.7 ± 0.9kJ/molCKirchner, Acree, et al., 1986AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
97.4 ± 1.2309.TVerevkin, Morgenthaler, et al., 1997Based on data from 294. - 326. K.; AC
85.5 ± 2.1293.ESTCoates and Sutton, 1948AC
86. ± 2.293.VCoates and Sutton, 1948, 2ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
20.42329.7Verevkin, Morgenthaler, et al., 1997AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meic and Baranovic, 1989
Meic, Z.; Baranovic, G., Vibrational spectra of trans-N-benzylideneaniline and its isotopomers, Pure Appl. Chem., 1989, 61, 2129. [all data]

Verevkin, Morgenthaler, et al., 1997
Verevkin, Sergey P.; Morgenthaler, Jens; Rüchardt, Christoph, Thermochemistry of imines: experimental standard molar enthalpies of formation, The Journal of Chemical Thermodynamics, 1997, 29, 10, 1175-1183, https://doi.org/10.1006/jcht.1997.0242 . [all data]

Kirchner, Acree, et al., 1986
Kirchner, J.J.; Acree, W.E., Jr.; Pilcher, G.; Shaofeng, L., Enthalpies of combustion of four N-phenylmethylene benzenamine N-oxide derivatives, of N-phenylmethylene benzenamine, and of trans-diphenyldiazene N-oxide: the dissociation enthalpy of the (N-O)bonds, J. Chem. Thermodyn., 1986, 18, 793-799. [all data]

Coates and Sutton, 1948
Coates, G.E.; Sutton, L.E., 235. The heats of formation of the ?N?N? and ?C?N? bonds, J. Chem. Soc., 1948, 1187, https://doi.org/10.1039/jr9480001187 . [all data]

Coates and Sutton, 1948, 2
Coates, G.E.; Sutton, L.E., The heats of formation of the -N=N- and >C=N- bonds, J. Chem. Soc., 1948, 1187-1196. [all data]


Notes

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