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Cyclohexanol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-352.0 ± 0.67kJ/molCacWiberg, Wasserman, et al., 1985Trifluoroacetolysis; ALS
Deltafliquid-350. ± 2.kJ/molCcbRabinovoch, Tel'noy, et al., 1962ALS
Deltafliquid-347.4 ± 2.2kJ/molCcbSellers and Sunner, 1962Reanalyzed by Cox and Pilcher, 1970, Original value = -348.2 kJ/mol; ALS
Deltafliquid-349.2 ± 0.2kJ/molCcbParks, Mosley, et al., 1950ALS
Deltafliquid-359.2kJ/molCcbKelley, 1929ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3730. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
liquid203.87J/mol*KN/AAdachi, Suga, et al., 1968DH
liquid199.6J/mol*KN/AKelley, 1929Average of values derived from measurements on both low and high temperature crystal forms down to 13 K, plus entropy of transition and fusion. Debye extrapolation below 13.5 K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
214.06298.15Mayer, Rachwalska, et al., 1990T = 170 to 320 K. Cp(liq) = -2223.2606 + 22.0059595T - 0.0691686793T2 + 0.0000763592T3 J/mol*K (298 to 320 K). Cp value caluculated from equation.; DH
209.99298.15Caceres-Alonso, Costas, et al., 1988DH
220.1298.Conti, Gianni, et al., 1976DH
212.297.95Petit and TerMinassian, 1974T = 297 to 428 K. Value is unsmoothed experimental datum.; DH
213.59300.Adachi, Suga, et al., 1968T = 14 to 320 K.; DH
202.5305.1Phillip, 1939DH
209.03298.15Kelley, 1929T = 13 to 300 K. Value is unsmoothed experimental datum.; DH
174.9290.Herz and Bloch, 1924DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg, Wasserman, et al., 1985
Wiberg, K.B.; Wasserman, D.J.; Martin, E.J.; Murcko, M.A., Enthalpies of hydration of alkenes. 3. Cycloalkenes, J. Am. Chem. Soc., 1985, 107, 6019-6022. [all data]

Rabinovoch, Tel'noy, et al., 1962
Rabinovoch, N.B.; Tel'noy, V.I.; Terman, L.M.; Kirillova, A.S.; Razuvaev, G.A., The heats of decomposition and formation of dicyclohexyl- and dimethylperoxidecarbonate, Dokl. Akad. Nauk SSSR, 1962, 143, 133-136. [all data]

Sellers and Sunner, 1962
Sellers, P.; Sunner, S., Heats of combustion of cyclic ketones and alcohols, Acta Chem. Scand., 1962, 16, 46-52. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Parks, Mosley, et al., 1950
Parks, G.S.; Mosley, J.R.; Peterson, P.V., Jr., Heats of combustion and formation of some organic compounds containing oxygen, J. Chem. Phys., 1950, 18, 152. [all data]

Kelley, 1929
Kelley, K.K., Cyclohexanol and the third law of thermodynamics, J. Am. Chem. Soc., 1929, 51, 1400-1406. [all data]

Adachi, Suga, et al., 1968
Adachi, K.; Suga, H.; Seki, S., Phase changes in crystalline and glassy-crystalline cyclohexanol, Bull. Chem. Soc. Japan, 1968, 41, 1073-1087. [all data]

Mayer, Rachwalska, et al., 1990
Mayer, J.; Rachwalska, M.; Sciesinska, E.; Sciesinski, J., On the polymorphism of solid cyclohexanol by adiabatic calorimetry and far infrared methods, J. Phys.(Paris), 1990, 51(9), 857-867. [all data]

Caceres-Alonso, Costas, et al., 1988
Caceres-Alonso, M.; Costas, M.; Andreoli-Ball, L.; Patterson, D., Steric effects on the self-association of branched and cyclic alcohols in inert solvents. Apparent heat capacities of secondary and tertiary alcohols in hydrocarbons, Can. J. Chem., 1988, 66, 989-998. [all data]

Conti, Gianni, et al., 1976
Conti, G.; Gianni, P.; Matteoli, E.; Mengheri, M., Capacita termiche molari di alcuni composti organici mono- e bifunzionali nel liquido puro e in soluzione acquosa a 25C, Chim. Ind. (Milan), 1976, 58, 225. [all data]

Petit and TerMinassian, 1974
Petit, J.C.; TerMinassian, L., Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, J. Chem. Thermodynam., 1974, 6, 1139-1152. [all data]

Phillip, 1939
Phillip, N.M., Adiabatic and isothermal compressibilities of liquids, Proc. Indian Acad. Sci., 1939, A9, 109-120. [all data]

Herz and Bloch, 1924
Herz, W.; Bloch, W., Physikalisch-chemische Untersuchungen an Verbindungen der Cyklohexanreihe, Z. Phys. Chem., 1924, 110, 23-39. [all data]


Notes

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