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trinitromethane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus292.KN/ALewis and Smyth, 1939Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Deltavap54.8kJ/molVCarpenter, Zimmer, et al., 1970ALS
Quantity Value Units Method Reference Comment
Deltasub45.2 ± 2.1kJ/molN/AMiroshnichenko and Vorob'eva, 1999AC
Deltasub46.0 ± 0.42kJ/molVMirishnichenko, Lebedev, et al., 1967Heat of combustion corrected for constant pressure; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
32.6303.AStephenson and Malanowski, 1987Based on data from 290. - 317. K. See also Miroshnichenko, Lebedev, et al., 1967.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lewis and Smyth, 1939
Lewis, G.L.; Smyth, C.P., The Dipole Moments and Structures of Ozone, Silicobromoform and Dichlorogermane, J. Am. Chem. Soc., 1939, 61, 3067-3070. [all data]

Carpenter, Zimmer, et al., 1970
Carpenter, G.A.; Zimmer, M.F.; Baroody, E.E.; Robb, R.A., Enthalpy of formation of bromotrinitromethane, J. Chem. Eng. Data, 1970, 15, 553-556. [all data]

Miroshnichenko and Vorob'eva, 1999
Miroshnichenko, E.O.; Vorob'eva, V.P., Thermochemical characteristics of nitroalkanes, Zh. Fiz. Khim., 1999, 73, 3, 419. [all data]

Mirishnichenko, Lebedev, et al., 1967
Mirishnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulevskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya., Thermochemistry of trinitromethane, Zh. Fiz. Khim., 1967, 41, 1477-1479. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Miroshnichenko, Lebedev, et al., 1967
Miroshnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulivskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya., Zh. Fiz. Khim., 1967, 41, 6, 1477. [all data]


Notes

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